{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/4864/jsonld#"}], "@id": "", "generatedAt": "06-06-26 00:28:53", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/4864/jsonld#", "@type": "sdo:scidataFramework", "uid": "77_110", "title": "Solubility data from IUPAC SDS Volume 77 (page ?) - Nitroethane with Uranyl nitrate hexahydrate", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Valerii P. Sazonov", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:constituent", "sdo:methodology", "sdo:mixture", "sdo:procedure", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "w3i:Chemistry", "w3i:PhysicalChemistry"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The analytical method was used. (2) was placed with the appropriate amount of pure (1) in a small flask. The contents of the flask were warmed to 30 to 50 \u00b0C, agitated with excess (2) for 15 min, and then placed in a constant temperature bath at 20 \u00b0C with intermittent shaking for 6 to 8 h. Crystallization from the supersaturated solution occurred, and when equilibrium was reached the solution was quickly decanted, filtered to remove the fine crystals, and placed in a stoppered flask at 20 \u00b0C before analysis.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Nitroethane", "formula": "C2H5NO2", "casrn": "79-24-3", "iupacname": "1-nitroethane", "inchikey": "MCSAJNNLRCFZED-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Uranyl nitrate hexahydrate", "formula": "UO2(NO3)2(6H2O)", "casrn": "13520-83-7", "inchikey": "WRIBVRZWDPGVQH-UHFFFAOYSA-N", "iupacname": "dioxouranium;bis(nitric acid);hexahydrate"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Nitroethane", "description": "Synthesized by standard method; thoroughly dried and fractionally distilled.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Uranium bis(nitrato-O)dioxohexahydrate", "description": "Source not specified; A. R. grade; not purified.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Nitroethane with Uranyl nitrate hexahydrate", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Warner, R. K.; Aust. J. Appl. Sci. 4, 581-9 (1953)."}, {"@id": "source/1/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 77 (page ?) - Nitroethane with Uranyl nitrate hexahydrate", "url": "https://doi.org/10.1063/1.1417522"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}