{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/4923/jsonld#"}], "@id": "", "generatedAt": "06-06-26 00:39:38", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/4923/jsonld#", "@type": "sdo:scidataFramework", "uid": "77_20", "title": "Solubility data from IUPAC SDS Volume 77 (page ?) - Nitroethane with 3-Methylpentane", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Nikolai I. Lisov", "role": "compiler"}, {"@id": "author/2/", "@type": "dc:creator", "name": "Valerii P. Sazonov", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:constituent", "sdo:methodology", "sdo:mixture", "sdo:procedure", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "w3i:Chemistry", "w3i:PhysicalChemistry"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The synthetic method was used. The critical separation temperatures were determined by visual observation of the appearance of a meniscus. Critical temperatures determined in separate closed tubes and in the viscometers agreed within experimental error. Solutions were prepared from weighed amounts of the pure components. All manipulations were carried out in a dry box to eliminate contamination by moisture.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Nitroethane", "formula": "C2H5NO2", "casrn": "79-24-3", "iupacname": "1-nitroethane", "inchikey": "MCSAJNNLRCFZED-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "3-Methylpentane", "formula": "C6H14", "casrn": "96-14-0", "iupacname": "3-methylpentane", "inchikey": "PFEOZHBOMNWTJB-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Nitroethane", "description": "Purified by double distillation and by preparative gas chromatography; purity 99.97 mole% by GLC.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "3-Methylpentane", "description": "Phillips; research grade; purity 99.99 mole%.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Nitroethane with 3-Methylpentane", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Stein, A.; Allegra, J. C.; Allen, G. F.; J. Chem. Phys. 55, 4265-9 (1971).", "doi": "10.1063/1.1676745"}, {"@id": "source/1/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 77 (page ?) - Nitroethane with 3-Methylpentane", "url": "https://doi.org/10.1063/1.1417522"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}