{"compilation": {"title": "Solubility data from IUPAC SDS Volume 59 (page ?) - Phenanthrene with Perfluoro-tri-n-butylamine", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "William E. Acree, Jr.", "sources": [{"citation": "McLaughlin, E.; Scott, R. L.; J. Phys. Chem. 1954, 76, 5276-5279.", "pubtype": "paper", "url": "https://doi.org/10.1021/ja01650a004"}], "system": "Phenanthrene with Perfluoro-tri-n-butylamine", "substances": [{"constituent": 1, "name": "Phenanthrene", "formula": "C14H10", "molweight": 178.229, "casrn": "85-01-8", "inchi": "InChI=1S/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H", "inchikey": "YNPNZTXNASCQKK-UHFFFAOYSA-N", "sample": "White Label, Eastman Kodak Company, Rochester, New York, USA, was recrystallized five times from ethanol to give a melting point of 101&deg;C."}, {"constituent": 2, "name": "Heptacosafluorotributanamine", "formula": "C12F27N", "molweight": 671.092, "casrn": "311-89-7", "inchi": "InChI=1S/C12F27N/c13-1(14,7(25,26)27)4(19,20)10(34,35)40(11(36,37)5(21,22)2(15,16)8(28,29)30)12(38,39)6(23,24)3(17,18)9(31,32)33", "inchikey": "RVZRBWKZFJCCIB-UHFFFAOYSA-N", "sample": "Purity not specified, Minnesota Mining & Manufacturing Company, USA, was distilled shortly before use."}], "method": "Constant temperature bath, a precision thermometer and uv/visible spectrometer. <br>Mixtures of known concentrations sealed in glass ampoules and pre-equilibrated for four days at an elevated temperature. Saturated solutions were then transferred to a special solubility flask and equilibrated for three days at desired temperature. Aliquots removed, diluted ten-fold with solvent and concentrations determined spectrophotometrically at 270 nm.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.50e+01", "significand": "2.50", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.92e-02", "significand": "2.92", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "9.708e-01", "significand": "9.708", "exponent": "-1", "sigfigs": "4", "unit": "1"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "3.50e+01", "significand": "3.50", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "4.89e-02", "significand": "4.89", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "9.511e-01", "significand": "9.511", "exponent": "-1", "sigfigs": "4", "unit": "1"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "4.50e+01", "significand": "4.50", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "7.22e-02", "significand": "7.22", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "9.278e-01", "significand": "9.278", "exponent": "-1", "sigfigs": "4", "unit": "1"}], "supplemental": []}]}]}}