{"compilation": {"title": "Solubility data from IUPAC SDS Volume 69 (page ?) - Ethanol with 2,4,4-Trimethyl-1-pentene and Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Adam Skrzecz", "sources": [{"citation": "Kretschmer, C. B.; Wiebe, R.; Ind. Eng. Chem. 37, 1130 (1945).", "pubtype": "paper", "url": "https://doi.org/10.1021/ie50431a033"}], "system": "Ethanol with 2,4,4-Trimethyl-1-pentene and Water", "substances": [{"constituent": 1, "name": "Ethanol", "formula": "C2H6O", "molweight": 46.0684, "casrn": "64-17-5", "inchi": "InChI=1S/C2H6O/c1-2-3/h3H,2H2,1H3", "inchikey": "LFQSCWFLJHTTHZ-UHFFFAOYSA-N", "sample": "Source not specified; anhydrous ethanol."}, {"constituent": 2, "name": "2,4,4-Trimethyl-1-pentene", "formula": "C8H16", "molweight": 112.213, "casrn": "107-39-1", "inchi": "InChI=1S/C8H16/c1-7(2)6-8(3,4)5/h1,6H2,2-5H3", "inchikey": "FXNDIJDIPNCZQJ-UHFFFAOYSA-N", "sample": "Source not specified."}, {"constituent": 3, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Source not specified."}], "method": "A glass tube with stirrer containing the ternary mixture was immersed in a bath, the temperature of which could be varied. Mixtures were prepared directly in the tube, by special pipettes at 15.5\u00b0C. Precautions to exclude moisture and to prevent evaporation were observed. No correction was made for the slight expansion in volume when alcohol was mixed with hydrocarbon. In the paper the experimental results were expressed as the water tolerance of the alcohol-hydrocarbon blend. For practical purposes water tolerance was defined as the volume percent of water which can be added before separation occurs.", "dataset": [{"series": 1, "title": "Compositions along the saturation curve", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "-4.50e+01", "significand": "-4.50", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.282e+02", "significand": "2.282", "exponent": "2", "sigfigs": "4", "unit": "K"}], "data": [], "supplemental": [{"property": "Mass fraction (1)", "number": "5.127e-01", "significand": "5.127", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mass fraction (2)", "number": "4.619e-01", "significand": "4.619", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "6.682e-01", "significand": "6.682", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "2.471e-01", "significand": "2.471", "exponent": "-1", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "-4.50e+01", "significand": "-4.50", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.282e+02", "significand": "2.282", "exponent": "2", "sigfigs": "4", "unit": "K"}], "data": [], "supplemental": [{"property": "Mass fraction (1)", "number": "2.671e-01", "significand": "2.671", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mass fraction (2)", "number": "7.219e-01", "significand": "7.219", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "4.515e-01", "significand": "4.515", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "5.010e-01", "significand": "5.010", "exponent": "-1", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "0e+00", "significand": "0.0", "exponent": "0", "sigfigs": "0", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.732e+02", "significand": "2.732", "exponent": "2", "sigfigs": "4", "unit": "K"}], "data": [], "supplemental": [{"property": "Mass fraction (1)", "number": "5.021e-01", "significand": "5.021", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mass fraction (2)", "number": "4.523e-01", "significand": "4.523", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "6.242e-01", "significand": "6.242", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "2.309e-01", "significand": "2.309", "exponent": "-1", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "0e+00", "significand": "0.0", "exponent": "0", "sigfigs": "0", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.732e+02", "significand": "2.732", "exponent": "2", "sigfigs": "4", "unit": "K"}], "data": [], "supplemental": [{"property": "Mass fraction (1)", "number": "2.648e-01", "significand": "2.648", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mass fraction (2)", "number": "7.158e-01", "significand": "7.158", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "4.355e-01", "significand": "4.355", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "4.832e-01", "significand": "4.832", "exponent": "-1", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "2.50e+01", "significand": "2.50", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.982e+02", "significand": "2.982", "exponent": "2", "sigfigs": "4", "unit": "K"}], "data": [], "supplemental": [{"property": "Mass fraction (1)", "number": "4.954e-01", "significand": "4.954", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mass fraction (2)", "number": "4.463e-01", "significand": "4.463", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "5.984e-01", "significand": "5.984", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "2.213e-01", "significand": "2.213", "exponent": "-1", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "2.50e+01", "significand": "2.50", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.982e+02", "significand": "2.982", "exponent": "2", "sigfigs": "4", "unit": "K"}], "data": [], "supplemental": [{"property": "Mass fraction (1)", "number": "2.634e-01", "significand": "2.634", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mass fraction (2)", "number": "7.120e-01", "significand": "7.120", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "4.258e-01", "significand": "4.258", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "4.725e-01", "significand": "4.725", "exponent": "-1", "sigfigs": "4", "unit": "1"}]}]}]}}