{"compilation": {"title": "Solubility data from IUPAC SDS Volume 72 (page ?) - Nitromethane with Benzene and Cyclohexane", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Suri, S. K.; Talanta 17, 577 (1970).", "pubtype": "paper", "url": "https://doi.org/10.1016/0039-9140(70)80005-4"}], "system": "Nitromethane with Benzene and Cyclohexane", "substances": [{"constituent": 1, "name": "Nitromethane", "formula": "CH3NO2 ", "molweight": 61.04, "casrn": "75-52-5", "inchi": "InChI=1S/CH3NO2/c1-2(3)4/h1H3", "inchikey": "LYGJENNIWJXYER-UHFFFAOYSA-N", "sample": "Source not specified; purified by methods as in Weissberger1; ρ(30°C) = 1125.0 g L-1,ρ(40°C) = 1110.8 g · L-1."}, {"constituent": 2, "name": "Benzene", "formula": "C6H6", "molweight": 78.1118, "casrn": "71-43-2", "inchi": "InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N", "sample": "Source not specified; purified by methods as in Weissberger1; ρ(30°C) = 868.5 g L-1, ρ(40°C) = 857.5 g·L-1."}, {"constituent": 3, "name": "Cyclohexane", "formula": "C6H12", "molweight": 84.1595, "casrn": "110-82-7", "inchi": "InChI=1S/C6H12/c1-2-4-6-5-3-1/h1-6H2", "inchikey": "XDTMQSROBMDMFD-UHFFFAOYSA-N", "sample": "Source not specified; purified by methods as in Weissberger1; ρ(30°C) = 769.4 g L-1.ρ(40°C) = 759.6 g·L-1 ."}], "method": "The titration method, as described in Dunnery and Atwood,2 was used. Solutions and solvents were thermally equilibrated and held at constant temperature during titrations. Enough solution was taken to give a titer of 10 to 20 mL.", "reference": {"citation": "Dunnery, D. A.; Atwood, G. R.; Talanta 15, 855 (1968).", "pubtype": "paper", "url": "https://doi.org/10.1016/0039-9140(68)80181-x"}, "dataset": [{"series": 1, "title": "Mutual solubility of nitromethane, benzene and cyclohexane", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "4.00e+01", "significand": "4.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.132e+02", "significand": "3.132", "exponent": "2", "sigfigs": "4", "unit": "K"}], "data": [{"property": "Mass fraction (1)", "number": "5.1e-02", "significand": "5.1", "exponent": "-2", "sigfigs": "2", "unit": "1"}, {"property": "Mass fraction (2)", "number": "1.5e-02", "significand": "1.5", "exponent": "-2", "sigfigs": "2", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "6.9e-02", "significand": "6.9", "exponent": "-2", "sigfigs": "2", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "1.6e-02", "significand": "1.6", "exponent": "-2", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "4.00e+01", "significand": "4.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.132e+02", "significand": "3.132", "exponent": "2", "sigfigs": "4", "unit": "K"}], "data": [{"property": "Mass fraction (1)", "number": "7.3e-02", "significand": "7.3", "exponent": "-2", "sigfigs": "2", "unit": "1"}, {"property": "Mass fraction (2)", "number": "8.9e-02", "significand": "8.9", "exponent": "-2", "sigfigs": "2", "unit": "1"}], "supplemental": [{"property": "Mole fraction - 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