{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/4458/jsonld#"}], "@id": "", "generatedAt": "04-18-26 20:40:24", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/4458/jsonld#", "@type": "sdo:scidataFramework", "uid": "72_134", "title": "Solubility data from IUPAC SDS Volume 72 (page ?) - Nitromethane with Benzene and Cyclohexane", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Valerii P. Sazonov", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:reference", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "obo:NCIT_C25206", "qudt:K", "sdo:numericvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The titration method, as described in Dunnery and Atwood,<sup>2</sup> was used. 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"chemical/2/", "@type": "sdo:chemical", "name": "Benzene", "description": "Source not specified; purified by methods as in Weissberger<sup>1</sup>; &rho;(30&deg;C) = 868.5 g L<sup>-1</sup>, &rho;(40&deg;C) = 857.5 g&middot;L<sup>-1</sup>.", "substance#": "substance/2/"}, {"@id": "chemical/3/", "@type": "sdo:chemical", "name": "Cyclohexane", "description": "Source not specified; purified by methods as in Weissberger<sup>1</sup>; &rho;(30&deg;C) = 769.4 g L<sup>-1</sup>.&rho;(40&deg;C) = 759.6 g&middot;L<sup>-1</sup> .", "substance#": "substance/3/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Nitromethane with Benzene and Cyclohexane", "type": "ternary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", 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