{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/4732/jsonld#"}], "@id": "", "generatedAt": "04-18-26 17:51:34", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/4732/jsonld#", "@type": "sdo:scidataFramework", "uid": "73_234", "title": "Solubility data from IUPAC SDS Volume 73 (page ?) - Copper(II) formate with Nickel formate, Zinc formate and Formic acid", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Tatiana A. Ageyeva", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:constituent", "sdo:methodology", "sdo:mixture", "sdo:procedure", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "afrl:0000270", "w3i:Chemistry", "w3i:PhysicalChemistry"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "Solubility values were determined by the freezing point method, but no details are given."}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "chemname": "Copper formate", "formula": "Cu(CHO2)2", "casrn": "544-19-4", "iupacname": "copper;diformate", "inchikey": "HFDWIMBEIXDNQS-UHFFFAOYSA-L"}, {"@id": "substance/2/", "@type": "sdo:substance", "chemname": "Nickel formate", "formula": "Ni(CHO2)2", "casrn": "3349-06-2", "iupacname": "nickel(2+);diformate", "inchikey": "HZPNKQREYVVATQ-UHFFFAOYSA-L"}, {"@id": "substance/3/", "@type": "sdo:substance", "chemname": "Zinc formate", "formula": "Zn(CHO2)2", "casrn": "557-41-5", "iupacname": "zinc;diformate", "inchikey": "XOBMCBQSUCOAOC-UHFFFAOYSA-L"}, {"@id": "substance/4/", "@type": "sdo:substance", "chemname": "Formic acid", "formula": "CH2O2", "casrn": "64-18-6", "iupacname": "formic acid", "inchikey": "BDAGIHXWWSANSR-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Copper formate", "description": "The copper, nickel and zinc salts were prepared by dissolving the carbonate in 90% formic acid. The copper and nickel salts were recrystallized from water and then dehydrated by heating the copper salt at 353 K and the nickel salt at 413 K. Nothing is stated about the purity of any of the salts. The formic acid was prepared by treating a c.p. product with B<sub>2</sub>O<sub>3</sub> and then distilling <i>in vacuo</i> until a product melting above 281.6 K was obtained.", "substance#": "substance/1/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Copper(II) formate with Nickel formate, Zinc formate and Formic acid", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/3/", "@type": "sdo:constituent", "chemical": "chemical 3", "chemical#": "chemical/3/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/4/", "@type": "sdo:constituent", "chemical": "chemical 4", "chemical#": "chemical/4/", "role": "solvent", "role#": "afrl:0000269"}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Kendall, J.; Adler, H.; J. Am. Chem. Soc. 43, 1470 (1921).", "doi": "10.1021/ja01440a010"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 73 (page ?) - Copper(II) formate with Nickel formate, Zinc formate and Formic acid", "url": "https://doi.org/10.1063/1.1354207"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}