{"compilation": {"title": "Solubility data from IUPAC SDS Volume 20 (page 172) - Chlorobenzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Jones, J. R.; Monk, C. B.; J. Chem. Soc. 1963, 2633-5.", "pubtype": "paper", "url": "https://doi.org/10.1039/jr9630002633"}], "system": "Chlorobenzene with Water", "substances": [{"constituent": 2, "name": "Chlorobenzene", "formula": "C6H5C1", "molweight": 112.557, "casrn": "108-90-7", "inchi": "InChI=1S/C6H5Cl/c7-6-4-2-1-3-5-6/h1-5H", "inchikey": "MVPPADPHJFYWMZ-UHFFFAOYSA-N", "sample": "Source not known, laboratory grade, dried over CaCI<sub>2</sub> and fractionally distilled before use."}, {"constituent": 1, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Tritiated."}], "method": "Tritiated water was shaken with bromobenzene in 1:10 volume ratios for 4 hours in a flask in a water thermostat bath. The water content was determined by tritium assay. The count rates were determined using a typical liquid scintillator solution technique.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.92e-03", "significand": "1.92", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Solubility (v/v) (1 in 2)", "number": "3.4e-01", "significand": "3.4", "exponent": "-1", "sigfigs": "2", "unit": "1"}, {"property": "Amount Concentration (1)", "number": "1.88e-02", "significand": "1.88", "exponent": "-2", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "3.0e+01", "significand": "3.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.239e-03", "significand": "2.239", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Solubility (v/v) (1 in 2)", "number": "3.95e-01", "significand": "3.95", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Amount Concentration (1)", "number": "2.182e-02", "significand": "2.182", "exponent": "-2", "sigfigs": "4", "unit": "mol/dm<sup>3</sup>"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.5e+01", "significand": "3.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.62e-03", "significand": "2.62", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Solubility (v/v) (1 in 2)", "number": "4.6e-01", "significand": "4.6", "exponent": "-1", "sigfigs": "2", "unit": "1"}, {"property": "Amount Concentration (1)", "number": "2.54e-02", "significand": "2.54", "exponent": "-2", "sigfigs": "3", "unit": "mol/dm<sup>3</sup>"}], "supplemental": []}]}]}}