{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 90) - Benzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Z. Maczynska, Andrzej Maczynski", "sources": [{"citation": "Hill, A. E.; J. Am. Chem. Soc. 1923, 45, 1143-55", "pubtype": "paper", "url": "https://doi.org/10.1021/ja01658a007"}], "system": "Benzene with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "not specified."}, {"constituent": 1, "name": "Benzene", "formula": "C6H6", "molweight": 78.1118, "casrn": "71-43-2", "inchi": "InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N", "sample": "source not specified; purified by recrystallization; dried over calcium chloride and finally over bright sodium wire; m.p. 54&deg;C or higher."}], "method": "A mixture of (1) and (2) was mechanically stirred at various temperatures and, after saturation was obtained, was transferred to small cylinders, treated with weighed amounts of silver perchlorate and the solubility of the salt in the mixed solvent determined at 25 \u00b0C. After a correction for the amount of (1) present in the solid phase, the original (2) content of the saturated solution could be determined from the reference curve.", "dataset": [{"series": 1, "title": "Solubility of water in benzene", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "5.4e+00", "significand": "5.4", "exponent": "0", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "3.4e-02", "significand": "3.4", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "1.5e-03", "significand": "1.5", "exponent": "-3", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "1.50e+01", "significand": "1.50", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "5.4e-02", "significand": "5.4", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "2.3e-03", "significand": "2.3", "exponent": "-3", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.50e+01", "significand": "2.50", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "7.3e-02", "significand": "7.3", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "3.2e-03", "significand": "3.2", "exponent": "-3", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "3.75e+01", "significand": "3.75", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "1.15e-01", "significand": "1.15", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "5.2e-03", "significand": "5.2", "exponent": "-3", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "5.00e+01", "significand": "5.00", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "1.56e-01", "significand": "1.56", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "6.7e-03", "significand": "6.7", "exponent": "-3", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "5.75e+01", "significand": "5.75", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "1.85e-01", "significand": "1.85", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "8.0e-03", "significand": "8.0", "exponent": "-3", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "6.50e+01", "significand": "6.50", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "2.30e-01", "significand": "2.30", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "9.9e-03", "significand": "9.9", "exponent": "-3", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 8, "conditions": [{"property": "Ambient temperature", "number": "6.95e+01", "significand": "6.95", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "2.65e-01", "significand": "2.65", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "1.14e-02", "significand": "1.14", "exponent": "-2", "sigfigs": "3", "unit": "1"}]}]}]}}