{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/615/jsonld#"}], "@id": "", "generatedAt": "04-18-26 13:37:13", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/615/jsonld#", "@type": "sdo:scidataFramework", "uid": "37_76", "title": "Solubility data from IUPAC SDS Volume 37 (page 112) - Benzene with Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Marie C. Haulait-Pirson", "role": "compiler"}, {"@id": "author/2/", "@type": "dc:creator", "name": "Glenn T. Hefter", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:constituent", "sdo:methodology", "sdo:mixture", "sdo:procedure", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "afrl:0000270", "w3i:Chemistry", "w3i:PhysicalChemistry"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "10 mL portions of (2) are pipetted into glass vials, following which, varying amounts of (1) were added to each bottle by direct weighing. The vials were shaken overnight. When two vials had been obtained, one clear and one with excess hyrocarbon and containing amounts differing by less than 1 mg, the two values were averaged and the mean taken as the amount solubilized."}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "chemname": "Benzene", "formula": "C6H6", "casrn": "71-43-2", "iupacname": "benzene", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "chemname": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Benzene", "description": "C.P. grade.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Water", "description": "distilled and boiled to remove CO<sub>2</sub>.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Benzene with Water", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "McBain, J. W.; Lissant, K. J.; J. Phys. Colloid. Chem. 1951, 55, 655-62.", "doi": "10.1021/j150488a004"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 37 (page 112) - Benzene with Water", "url": "https://iupac.github.io/SolubilityDataSeries/volumes/SDS-37.pdf"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}