Components:
Original Measurements
Jones, J. R.; Monk, C. B.; J. Chem. Soc. 1963, 2633-5.
Variables:
Ambient temperature: Temperature
Prepared by:
Method/Apparatus/Procedure:
Tritiated water was shaken with 1,2-dichlorobenzene in 1:10 volume ratios for 4 hours in a flask in a water thermostat bath. The water content was determined by tritium assay. The count rates were determined using a typical liquid scintillator solution technique.
Source and Purity of Materials:
- Tritiated.
- Source not known, Laboratory grade, dried over CaCl2 and fractionally distilled before use.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): ±5%.
Experimental Values:
| T (°C) | x1 | S1:2a | C1 (mol/dm3) |
|---|---|---|---|
| 25.0 | 2.00 x 10-3 | 3.2 x 10-1 | 1.77 x 10-2 |
| 30.0 | 2.348 x 10-3 | 3.75 x 10-1 | 2.072 x 10-2 |
| 35.0 | 2.667 x 10-3 | 4.25 x 10-1 | 2.344 x 10-2 |
(a) Reported. (b) Calculated by F. W. Getzen. (c) Calculated by the compiler.
