Components:

(1) Naphthalene, C10H8; [91-20-3] NIST WebBook
(2) 4-Nitrophenol, C6H5NO3; [100-02-7] NIST WebBook

Original Measurements

Kremann, R.; Monatsch. Chem. 1904, 25, 1271-1292.

Variables:

Ambient temperature: Temperature

Prepared by:

W.E. Acree, Jr.

Method/Apparatus/Procedure:

Binary mixtures prepared by weight. While the experimental details were not given in the paper, compiler speculates (based upon quantity of material used) that the sample was sealed in a glass container, temperature slowly varied, and the phase diagram determined by visually noting the temperature at which the last/first crystal of solid disappeared/appeared.

Source and Purity of Materials:
  1. Purity and chemical source were not specified in paper.
  2. Purity and chemical source were not specified in paper.
Estimated Errors:

Ambient temperature: T/K: precision ±0.2 (compiler). x1: ±0.002 (compiler).

Experimental Values:
T (K) x1 x2
386.2 0.0 1.0
380.2 1.00 x 10-1 9.00 x 10-1
375.2 2.01 x 10-1 7.99 x 10-1
368.2 3.14 x 10-1 6.86 x 10-1
365.2 3.93 x 10-1 6.07 x 10-1
362.2 4.46 x 10-1 5.54 x 10-1
360.2 5.04 x 10-1 4.96 x 10-1
358.2 5.39 x 10-1 4.61 x 10-1
357.5 5.54 x 10-1 4.46 x 10-1
355.5 5.92 x 10-1 4.08 x 10-1
354.2 6.19 x 10-1 3.81 x 10-1
348.2 7.31 x 10-1 2.69 x 10-1
348.2 8.19 x 10-1 1.81 x 10-1
351.2 9.37 x 10-1 6.3 x 10-2
353.7 1.0 0.0

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