Components:
(1) Naphthalene,
C10H8; [91-20-3]
NIST WebBook
(2) Isoquinoline,
C9H7N; [119-65-3]
NIST WebBook
Original Measurements
Kravchenko, V. M.; Pastukhova, I. S.; J. Appl. Chem. USSR 1952, 25, 343-350.
Variables:
Ambient temperature: 297.2 - 353.2 K
Prepared by:
Method/Apparatus/Procedure:
Phase diagram was determined using a thermal analysis method (described in detail in V.M. Kravchenko, J. Phys. Chem. U.S.S.R. 1939, 13, 133), supplemented by visual observations.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper, was recrystallized before use.
- Purity and chemical source were not specified in paper, was distilled before use.
Estimated Errors:
Ambient temperature: T/K: precision ±0.2 (compiler). x1: ±0.002 (compiler).
References
1 Kravchenko, V. M.; Zh. Fiz. Khim. 1939, 13, 133-145.
Experimental Values:
| T (K) | T (K) | x1 | x2 |
|---|---|---|---|
| 297.2 | 297.2 | 0.0 | 1.0 |
| 301.2 | 299.7 | 4.7 x 10-2 | 9.53 x 10-1 |
| 306.2 | 304.2 | 1.09 x 10-1 | 8.91 x 10-1 |
| 314.2 | 311.2 | 2.08 x 10-1 | 7.92 x 10-1 |
| 319.7 | 316.2 | 2.97 x 10-1 | 7.03 x 10-1 |
| 326.7 | 323.2 | 4.12 x 10-1 | 5.88 x 10-1 |
| 331.2 | 327.2 | 5.00 x 10-1 | 5.00 x 10-1 |
| 336.7 | 333.2 | 6.02 x 10-1 | 3.98 x 10-1 |
| 341.2 | 338.2 | 7.00 x 10-1 | 3.00 x 10-1 |
| 345.2 | 343.2 | 8.00 x 10-1 | 2.00 x 10-1 |
| 349.2 | 348.2 | 9.04 x 10-1 | 9.6 x 10-2 |
| 353.2 | 353.2 | 1.0 | 0.0 |
(a) Phase Diagram, given in the original paper, shows formation of a complete series of solid solutions. Melting points of binary mixtures lie between those of the two pure components. Tin refers to the temperature at which crystallization begins; Tfin is the temperature at which crystallization of the solid solution concludes.
