Components:

(1) Carbon dioxide, CO2; [124-38-9] NIST WebBook
(2) Potassium nitrate, KNO3; [7757-79-1] NIST WebBook
(3) Water, H2O; [7732-18-5] NIST WebBook

Original Measurements

Setchenow, J.; Nouv. Mem. Soc. Imp. Nat. Moscow 1889, 15, 203-74.

Variables:

Ambient temperature: 288.35 K
Amount concentration (2): C2/mol dm-3 = 0 - 2.325

Prepared by:

P. Scharlin

Method/Apparatus/Procedure:

See other data sheets on J. Setchenow papers.

Source and Purity of Materials:
  1. See other data sheets on J. Setchenow papers.
Estimated Errors:

Ambient temperature: See other data sheets on J. Setchenow papers.

Experimental Values:
Note: Initial solution: 23.51 g KNO3 + 90.10 cm3 water to make 100 cm3 of sln.
T (K) T (°C) C2 (mol/dm3)a α (cm3(g) cm-3(l) atm-1)b DF Kscc (dm3/mol)a,c
288.35 15.2 0.0 1.009 -
288.35 15.2 5.813 x 10-1 9.59 x 10-1 4.0 3.80 x 10-2
288.35 15.2 1.163 8.905 x 10-1 2.0 4.66 x 10-2
288.35 15.2 2.325 7.81 x 10-1 1.0 4.78 x 10-2

(a) Calculated by the compiler. (b) α = Bunsen coefficient [cm3 (STP) cm-3 atm-1]. (c) Kscc = Setchenow salt effect parameter; Kscc = (1/c2) lg(αo/α).

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