Components:

(1) Tetrachloroethene, C2Cl4; [127-18-4] NIST WebBook
(2) Water, H2O; [7732-18-5] NIST WebBook

Original Measurements

Moiseeva, L. M.; Stepanova, G. G.; Pukhonto, A. N.; Sov. Chem. Ind. 9, 453 (1977).

Variables:

Ambient temperature: 293 K

Prepared by:

A.L. Horvath

Method/Apparatus/Procedure:

Water was saturated with tetrachloroethene in a thermostatted round bottomed flask fitted with a stirrer and a mercury seal. The stirring was continued for several days until equilibrium between the two liquids was established. The analysis of the saturated aqueous solution was carried out using a gas chromatograph. The column was filled with Cromosorb W, impregnated with Apiezon I. The helium carrier gas flow rate was 500 cm3/minute.

Source and Purity of Materials:
  1. Type "pure" (METU 6-00 No. 6590-70), redistilled and checked by GLC.
  2. Distilled.
Estimated Errors:

Ambient temperature: ±0.2 K.
Mass concentration (m/v) (1): ±1.74%.

Experimental Values:
T (°C) ρ (g/L) 100w1a x1a
20.0 2.065 x 10-1 2.069 x 10-2 2.25 x 10-5

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