Components:

(1) 1-Butanol, C4H10O; [71-36-3] NIST WebBook
(2) Hexane, C6H14; [110-54-3] NIST WebBook
(3) Water, H2O; [7732-18-5] NIST WebBook

Original Measurements

Morozov, A. V.; Sarkisov, A. G.;Turovskii, V. B.; Ilyaskin, V. I.; Dep. Doc. VINITI 102-78, 1 (1978).

Variables:

Ambient temperature: 333 K

Prepared by:

A. Skrzecz

Method/Apparatus/Procedure:

The titration method was used. The composition of the organic-rich phase was presented; the composition of the water-rich phase was not investigated.

Source and Purity of Materials:
  1. Source not specified; dried, distilled, n(20°C,D)=1.3991, d(25°C,4°C)=0.8010.
  2. Source not specified; twice distilled, n(20°C,D)=1.3748, d(25°C,4°C)=0.6544.
  3. Doubly distilled.
Estimated Errors:

Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.

Experimental Values:
Compositions along the saturation curve
T (°C) T (K) x1 x2 w1 w2
60.0 333.2 4.875 x 10-1 4.25 x 10-2 7.487 x 10-1 7.59 x 10-2
60.0 333.2 4.890 x 10-1 4.69 x 10-2 7.451 x 10-1 8.31 x 10-2
60.0 333.2 5.055 x 10-1 1.087 x 10-1 6.966 x 10-1 1.742 x 10-1
60.0 333.2 4.980 x 10-1 1.840 x 10-1 6.310 x 10-1 2.711 x 10-1
60.0 333.2 4.193 x 10-1 3.607 x 10-1 4.700 x 10-1 4.701 x 10-1
60.0 333.2 2.902 x 10-1 5.827 x 10-1 2.906 x 10-1 6.784 x 10-1
60.0 333.2 1.010 x 10-1 8.340 x 10-1 9.30 x 10-2 8.925 x 10-1

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