Components:
(1) Copoly(pyromellitic dianhydride-oxydianiline),
(C22H10N2O5)n; [25036-53-7]
NIST WebBook
(2) Polyarylate,
C24H33ClFN7O7S2; [25639-68-3]
NIST WebBook
Original Measurements
Ranade, G. R.; Chandler, R.; Plank, C. A.; Laukhauf, W. L. S.; Polym. Eng. Sci. 25, 164 (1985).
Variables:
Ambient temperature: 298 - 336 K
Pressure: 0 - 90 kPa
Prepared by:
Method/Apparatus/Procedure:
Sorption was measured using a gravimetric technique (a McBain quartz spring balance). For detailed description of the experimental procedure see Ref. 1.
Source and Purity of Materials:
- Polyarylate (Ardel-D 100): Union Carbide, copolyester of bisphenol A with 50/50 mixture of iso- and terephthalic acid. Density 1.21 g/cm3, Mn = 12300, M,=29 800.
Estimated Errors:
Ambient temperature: Precision in T: ±0.1 K
References
1 Ranade, O. R.; Nadgir, V. M.; Plank, C. A.; Laukhuf, W. L. S.; J. Appl. Polym. Sci. 28, 201 (1983).
Experimental Values:
Dual mode sorption parameters for sulfur dioxide inpolyarylate
| T (K) | H (cm3(g) cm-3(s) atm-1) | C'H (cm3/cm3) | b (atm-1) |
|---|---|---|---|
| 278.0 | 1.78 | 4.69 | 1.6 |
| 298.0 | 32.47 | 16.06 | 16.03 |
| 313.0 | 14.99 | 25.07 | 5.02 |
| 328.0 | 5.01 | 30.01 | 2.77 |
| 336.0 | 3.5 | 24.04 | 1.26 |
None


