Components:

(1) Copoly(pyromellitic dianhydride-oxydianiline), (C22H10N2O5)n; [25036-53-7] NIST WebBook
(2) Polyarylate, C24H33ClFN7O7S2; [25639-68-3] NIST WebBook

Original Measurements

Ranade, G. R.; Chandler, R.; Plank, C. A.; Laukhauf, W. L. S.; Polym. Eng. Sci. 25, 164 (1985).

Variables:

Ambient temperature: 298 - 336 K
Pressure: 0 - 90 kPa

Prepared by:

S.M. Shishatski

Method/Apparatus/Procedure:

Sorption was measured using a gravimetric technique (a McBain quartz spring balance). For detailed description of the experimental procedure see Ref. 1.

Source and Purity of Materials:
  1. Polyarylate (Ardel-D 100): Union Carbide, copolyester of bisphenol A with 50/50 mixture of iso- and terephthalic acid. Density 1.21 g/cm3, Mn = 12300, M,=29 800.
Estimated Errors:

Ambient temperature: Precision in T: ±0.1 K

References

1 Ranade, O. R.; Nadgir, V. M.; Plank, C. A.; Laukhuf, W. L. S.; J. Appl. Polym. Sci. 28, 201 (1983).

Experimental Values:
Dual mode sorption parameters for sulfur dioxide inpolyarylate
T (K) H (cm3(g) cm-3(s) atm-1) C'H (cm3/cm3) b (atm-1)
278.0 1.78 4.69 1.6
298.0 32.47 16.06 16.03
313.0 14.99 25.07 5.02
328.0 5.01 30.01 2.77
336.0 3.5 24.04 1.26

Solubility graph

None

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