Components:

(1) Nitromethane, CH3NO2 ; [75-52-5] NIST WebBook
(2) Diiodomethane, CH2I2; [75-11-6] NIST WebBook
(3) 1,2-Ethanediol, C2H6O2 ; [107-21-1] NIST WebBook
(4) Cyclohexane, C6H12; [110-82-7] NIST WebBook

Original Measurements

Sazonov, V. P.; Zhilyaeva, I. N.; Gudkina, L. V.; Zh. Fiz. Khim. 49, 1594-5 (1975).

Variables:

Ambient temperature: 281 - 417 K

Prepared by:

N.V. Sazonov, V.P. Sazonov

Method/Apparatus/Procedure:

The synthetic method was used. Temperatures of phase transitions were determined both on heating and cooling of the mixtures, and the average temperature value obtained was taken. Measurements were carried out in a thermostat containing silicone oil at temperatures above 80 °C.

Source and Purity of Materials:
  1. Source not specified; pure grade reagent; dried and twice distilled in glass packed column.
  2. Source not specified; analytical purity; dried and twice distilled in presence of zinc dust under vacuum.
  3. Analytical purity; dried and twice distilled under vacuum; 0.03 mass% water by the Karl Fischer analysis.
  4. Source not specified; dried and fractionated.
Estimated Errors:

Ambient temperature: ±0.01 K (283 K to 313 K); ±0.05 K (313 K to 343 K); ±0.1 K (above 343 K).

Experimental Values:
Note: The temperatures of phase transitions were determined in quaternary mixtures with a constant mass content of (3), respectively, 5.0, 10.0, 20.0, 30.0, 40.0, and 50.0 mass %, and with a constant mass content of (1), respectively, 9.5, 19.0, and 38.0; 9.0, 18.0 and 36.0; 4.0, 8.0, 16.0 and 32.0; 21.0 and 28.0; 6.0, 12.0 and 24.0; 5.0, 10.0, and 20.0 mass %, and in quaternary mixtures with a constant mass content of (3), respectively, 5.0, 10.0, and 20.0, and with a constant mass relationship of (2) and (4), namely 72.5:27.5 ratio. L1 nitromethane-rich phase; L2 diiodomethane-rich phase; L3 ethanediol-rich phase; L4 cyclohexane-rich phase. The phase which is being dissolved is indicated in the table.
Table 1. Solubility temperatures of the four liquid phases
T (°C) T (K) w1 w2 w3 x1 x2 x3
10.42 283.57 9.5 x 10-2 5.13 x 10-1 5.0 x 10-2 1.87 x 10-1 2.30 x 10-1 9.6 x 10-2
11.12 284.27 9.5 x 10-2 5.35 x 10-1 5.0 x 10-2 1.91 x 10-1 2.44 x 10-1 9.9 x 10-2
11.62 284.77 9.5 x 10-2 5.56 x 10-1 5.0 x 10-2 1.95 x 10-1 2.60 x 10-1 1.01 x 10-1
11.96 285.11 9.5 x 10-2 5.77 x 10-1 5.0 x 10-2 1.99 x 10-1 2.76 x 10-1 1.03 x 10-1
12.05 285.2 9.5 x 10-2 6.62 x 10-1 5.0 x 10-2 2.19 x 10-1 3.47 x 10-1 1.13 x 10-1
12.12 285.27 9.5 x 10-2 5.98 x 10-1 5.0 x 10-2 2.04 x 10-1 2.92 x 10-1 1.05 x 10-1
12.23 285.38 9.5 x 10-2 6.41 x 10-1 5.0 x 10-2 2.13 x 10-1 3.28 x 10-1 1.11 x 10-1
12.37 285.52 9.5 x 10-2 6.20 x 10-1 5.0 x 10-2 2.08 x 10-1 3.10 x 10-1 1.08 x 10-1
9.08 282.23 1.90 x 10-1 4.56 x 10-1 5.0 x 10-2 3.37 x 10-1 1.85 x 10-1 8.7 x 10-2
9.34 282.49 1.90 x 10-1 6.46 x 10-1 5.0 x 10-2 4.05 x 10-1 3.14 x 10-1 1.05 x 10-1
11.07 284.22 1.90 x 10-1 4.94 x 10-1 5.0 x 10-2 3.49 x 10-1 2.07 x 10-1 9.0 x 10-2
11.42 284.57 1.90 x 10-1 6.27 x 10-1 5.0 x 10-2 3.97 x 10-1 2.99 x 10-1 1.03 x 10-1
11.62 284.77 1.90 x 10-1 5.13 x 10-1 5.0 x 10-2 3.55 x 10-1 2.18 x 10-1 9.2 x 10-2
12.07 285.22 1.90 x 10-1 5.32 x 10-1 5.0 x 10-2 3.61 x 10-1 2.31 x 10-1 9.4 x 10-2
12.12 285.27 1.90 x 10-1 6.08 x 10-1 5.0 x 10-2 3.89 x 10-1 2.84 x 10-1 1.01 x 10-1
12.23 285.38 1.90 x 10-1 5.51 x 10-1 5.0 x 10-2 3.68 x 10-1 2.43 x 10-1 9.5 x 10-2
12.23 285.38 1.90 x 10-1 5.70 x 10-1 5.0 x 10-2 3.75 x 10-1 2.56 x 10-1 9.7 x 10-2
12.35 285.5 1.90 x 10-1 5.89 x 10-1 5.0 x 10-2 3.82 x 10-1 2.70 x 10-1 9.9 x 10-2
8.28 281.43 3.80 x 10-1 4.99 x 10-1 5.0 x 10-2 6.39 x 10-1 1.91 x 10-1 8.3 x 10-2
9.52 282.67 3.80 x 10-1 3.99 x 10-1 5.0 x 10-2 5.90 x 10-1 1.41 x 10-1 7.6 x 10-2
10.97 284.12 3.80 x 10-1 4.13 x 10-1 5.0 x 10-2 5.96 x 10-1 1.48 x 10-1 7.7 x 10-2
11.17 284.32 3.80 x 10-1 4.85 x 10-1 5.0 x 10-2 6.32 x 10-1 1.84 x 10-1 8.2 x 10-2
11.92 285.07 3.80 x 10-1 4.28 x 10-1 5.0 x 10-2 6.03 x 10-1 1.55 x 10-1 7.8 x 10-2
12.28 285.43 3.80 x 10-1 4.70 x 10-1 5.0 x 10-2 6.24 x 10-1 1.76 x 10-1 8.1 x 10-2
12.33 285.48 3.80 x 10-1 4.42 x 10-1 5.0 x 10-2 6.10 x 10-1 1.62 x 10-1 7.9 x 10-2
12.43 285.58 3.80 x 10-1 4.56 x 10-1 5.0 x 10-2 6.17 x 10-1 1.69 x 10-1 8.0 x 10-2
9.58 282.73 1.80 x 10-1 4.32 x 10-1 1.00 x 10-1 3.07 x 10-1 1.68 x 10-1 1.68 x 10-1
10.53 283.68 1.80 x 10-1 4.50 x 10-1 1.00 x 10-1 3.12 x 10-1 1.78 x 10-1 1.70 x 10-1
10.53 283.68 1.80 x 10-1 6.12 x 10-1 1.00 x 10-1 3.63 x 10-1 2.81 x 10-1 1.98 x 10-1
11.43 284.58 1.80 x 10-1 4.68 x 10-1 1.00 x 10-1 3.17 x 10-1 1.88 x 10-1 1.73 x 10-1
11.97 285.12 1.80 x 10-1 4.86 x 10-1 1.00 x 10-1 3.22 x 10-1 1.98 x 10-1 1.76 x 10-1
12.28 285.43 1.80 x 10-1 5.94 x 10-1 1.00 x 10-1 3.56 x 10-1 2.68 x 10-1 1.95 x 10-1
12.28 285.43 1.80 x 10-1 5.76 x 10-1 1.00 x 10-1 3.50 x 10-1 2.56 x 10-1 1.91 x 10-1
12.38 285.53 1.80 x 10-1 5.04 x 10-1 1.00 x 10-1 3.27 x 10-1 2.09 x 10-1 1.79 x 10-1
12.49 285.64 1.80 x 10-1 5.22 x 10-1 1.00 x 10-1 3.33 x 10-1 2.20 x 10-1 1.82 x 10-1
12.51 285.66 1.80 x 10-1 5.58 x 10-1 1.00 x 10-1 3.44 x 10-1 2.43 x 10-1 1.88 x 10-1
12.53 285.68 1.80 x 10-1 5.40 x 10-1 1.00 x 10-1 3.38 x 10-1 2.31 x 10-1 1.85 x 10-1
8.83 281.98 3.60 x 10-1 4.72 x 10-1 1.00 x 10-1 5.85 x 10-1 1.75 x 10-1 1.60 x 10-1
9.71 282.86 3.60 x 10-1 3.78 x 10-1 1.00 x 10-1 5.44 x 10-1 1.30 x 10-1 1.49 x 10-1
10.92 284.07 3.60 x 10-1 3.91 x 10-1 1.00 x 10-1 5.49 x 10-1 1.36 x 10-1 1.50 x 10-1
11.37 284.52 3.60 x 10-1 4.59 x 10-1 1.00 x 10-1 5.79 x 10-1 1.68 x 10-1 1.58 x 10-1
11.86 285.01 3.60 x 10-1 4.05 x 10-1 1.00 x 10-1 5.55 x 10-1 1.42 x 10-1 1.52 x 10-1
12.39 285.54 3.60 x 10-1 4.46 x 10-1 1.00 x 10-1 5.73 x 10-1 1.62 x 10-1 1.56 x 10-1
12.43 285.58 3.60 x 10-1 4.19 x 10-1 1.00 x 10-1 5.61 x 10-1 1.49 x 10-1 1.53 x 10-1
12.54 285.69 3.60 x 10-1 4.32 x 10-1 1.00 x 10-1 5.67 x 10-1 1.55 x 10-1 1.55 x 10-1
9.9 283.05 1.60 x 10-1 4.00 x 10-1 2.00 x 10-1 2.57 x 10-1 1.47 x 10-1 3.16 x 10-1
10.4 283.55 1.60 x 10-1 5.44 x 10-1 2.00 x 10-1 2.91 x 10-1 2.25 x 10-1 3.57 x 10-1
11.45 284.6 1.60 x 10-1 4.16 x 10-1 2.00 x 10-1 2.61 x 10-1 1.54 x 10-1 3.20 x 10-1
11.51 284.66 1.60 x 10-1 5.28 x 10-1 2.00 x 10-1 2.87 x 10-1 2.16 x 10-1 3.52 x 10-1
11.81 284.96 1.60 x 10-1 4.32 x 10-1 2.00 x 10-1 2.64 x 10-1 1.62 x 10-1 3.25 x 10-1
12.0 285.15 1.60 x 10-1 5.12 x 10-1 2.00 x 10-1 2.83 x 10-1 2.06 x 10-1 3.47 x 10-1
12.15 285.3 1.60 x 10-1 4.48 x 10-1 2.00 x 10-1 2.67 x 10-1 1.71 x 10-1 3.29 x 10-1
12.35 285.5 1.60 x 10-1 4.64 x 10-1 2.00 x 10-1 2.71 x 10-1 1.79 x 10-1 3.33 x 10-1
12.4 285.55 1.60 x 10-1 4.96 x 10-1 2.00 x 10-1 2.79 x 10-1 1.97 x 10-1 3.43 x 10-1
12.42 285.57 1.60 x 10-1 4.80 x 10-1 2.00 x 10-1 2.75 x 10-1 1.88 x 10-1 3.38 x 10-1
9.6 282.75 3.20 x 10-1 3.36 x 10-1 2.00 x 10-1 4.58 x 10-1 1.10 x 10-1 2.82 x 10-1
10.61 283.76 3.20 x 10-1 3.48 x 10-1 2.00 x 10-1 4.63 x 10-1 1.15 x 10-1 2.84 x 10-1
11.25 284.4 3.20 x 10-1 4.08 x 10-1 2.00 x 10-1 4.83 x 10-1 1.41 x 10-1 2.97 x 10-1
11.7 284.85 3.20 x 10-1 3.60 x 10-1 2.00 x 10-1 4.66 x 10-1 1.20 x 10-1 2.87 x 10-1
12.2 285.35 3.20 x 10-1 3.96 x 10-1 2.00 x 10-1 4.79 x 10-1 1.35 x 10-1 2.95 x 10-1
12.41 285.56 3.20 x 10-1 3.84 x 10-1 2.00 x 10-1 4.75 x 10-1 1.30 x 10-1 2.92 x 10-1
12.45 285.6 3.20 x 10-1 3.72 x 10-1 2.00 x 10-1 4.71 x 10-1 1.25 x 10-1 2.89 x 10-1
10.05 283.2 2.40 x 10-1 2.52 x 10-1 4.00 x 10-1 3.12 x 10-1 7.5 x 10-2 5.11 x 10-1
11.15 284.3 2.40 x 10-1 2.61 x 10-1 4.00 x 10-1 3.14 x 10-1 7.8 x 10-2 5.14 x 10-1
11.35 284.5 2.40 x 10-1 3.06 x 10-1 4.00 x 10-1 3.23 x 10-1 9.4 x 10-2 5.30 x 10-1
12.1 285.25 2.40 x 10-1 2.70 x 10-1 4.00 x 10-1 3.16 x 10-1 8.1 x 10-2 5.17 x 10-1
12.37 285.52 2.40 x 10-1 2.97 x 10-1 4.00 x 10-1 3.21 x 10-1 9.1 x 10-2 5.27 x 10-1
12.48 285.63 2.40 x 10-1 2.79 x 10-1 4.00 x 10-1 3.18 x 10-1 8.4 x 10-2 5.20 x 10-1
12.56 285.71 2.40 x 10-1 2.88 x 10-1 4.00 x 10-1 3.19 x 10-1 8.7 x 10-2 5.24 x 10-1
10.08 283.23 2.00 x 10-1 2.10 x 10-1 5.00 x 10-1 2.49 x 10-1 5.9 x 10-2 6.11 x 10-1
11.41 284.56 2.00 x 10-1 2.18 x 10-1 5.00 x 10-1 2.50 x 10-1 6.2 x 10-2 6.14 x 10-1
11.62 284.77 2.00 x 10-1 2.55 x 10-1 5.00 x 10-1 2.56 x 10-1 7.4 x 10-2 6.28 x 10-1
12.17 285.32 2.00 x 10-1 2.25 x 10-1 5.00 x 10-1 2.51 x 10-1 6.4 x 10-2 6.17 x 10-1
12.38 285.53 2.00 x 10-1 2.47 x 10-1 5.00 x 10-1 2.54 x 10-1 7.2 x 10-2 6.26 x 10-1
12.45 285.6 2.00 x 10-1 2.32 x 10-1 5.00 x 10-1 2.52 x 10-1 6.7 x 10-2 6.19 x 10-1
12.51 285.66 2.00 x 10-1 2.40 x 10-1 5.00 x 10-1 2.53 x 10-1 6.9 x 10-2 6.23 x 10-1
12.57 285.72 8.6 x 10-2 6.26 x 10-1 5.0 x 10-2 1.91 x 10-1 3.17 x 10-1 1.09 x 10-1
12.62 285.77 9.5 x 10-2 6.20 x 10-1 5.0 x 10-2 2.08 x 10-1 3.10 x 10-1 1.08 x 10-1
12.62 285.77 1.15 x 10-1 6.05 x 10-1 5.0 x 10-2 2.45 x 10-1 2.94 x 10-1 1.05 x 10-1
12.47 285.62 1.09 x 10-1 5.74 x 10-1 1.00 x 10-1 2.20 x 10-1 2.64 x 10-1 1.98 x 10-1
12.47 285.62 1.35 x 10-1 5.55 x 10-1 1.00 x 10-1 2.64 x 10-1 2.47 x 10-1 1.92 x 10-1
12.38 285.53 1.34 x 10-1 4.83 x 10-1 2.00 x 10-1 2.34 x 10-1 1.92 x 10-1 3.43 x 10-1
12.45 285.6 1.04 x 10-1 5.05 x 10-1 2.00 x 10-1 1.87 x 10-1 2.08 x 10-1 3.55 x 10-1
12.48 285.63 9.8 x 10-2 5.09 x 10-1 2.00 x 10-1 1.78 x 10-1 2.11 x 10-1 3.57 x 10-1
12.49 285.64 1.16 x 10-1 4.96 x 10-1 2.00 x 10-1 2.06 x 10-1 2.01 x 10-1 3.50 x 10-1

(a) Critical opalescence.

Table 2. Solubility temperatures of the three liquid phases 
T (°C) T (K) w1 w2 w3 x1 x2 x3
10.01 283.16 9.5 x 10-2 7.27 x 10-1 5.0 x 10-2 2.36 x 10-1 4.11 x 10-1 1.22 x 10-1
11.02 284.17 9.5 x 10-2 7.05 x 10-1 5.0 x 10-2 2.30 x 10-1 3.89 x 10-1 1.19 x 10-1
11.92 285.07 9.5 x 10-2 6.84 x 10-1 5.0 x 10-2 2.24 x 10-1 3.68 x 10-1 1.16 x 10-1
12.76 285.91 9.5 x 10-2 6.62 x 10-1 5.0 x 10-2 2.19 x 10-1 3.47 x 10-1 1.13 x 10-1
14.31 287.46 9.5 x 10-2 6.41 x 10-1 5.0 x 10-2 2.13 x 10-1 3.28 x 10-1 1.11 x 10-1
15.22 288.37 9.5 x 10-2 6.20 x 10-1 5.0 x 10-2 2.08 x 10-1 3.10 x 10-1 1.08 x 10-1
17.43 290.58 9.5 x 10-2 5.98 x 10-1 5.0 x 10-2 2.04 x 10-1 2.92 x 10-1 1.05 x 10-1
18.21 291.36 9.5 x 10-2 5.77 x 10-1 5.0 x 10-2 1.99 x 10-1 2.76 x 10-1 1.03 x 10-1
22.36 295.51 9.5 x 10-2 5.56 x 10-1 5.0 x 10-2 1.95 x 10-1 2.60 x 10-1 1.01 x 10-1
23.52 296.67 9.5 x 10-2 5.35 x 10-1 5.0 x 10-2 1.91 x 10-1 2.44 x 10-1 9.9 x 10-2
24.67 297.82 9.5 x 10-2 5.13 x 10-1 5.0 x 10-2 1.87 x 10-1 2.30 x 10-1 9.6 x 10-2
22.67 295.82 1.90 x 10-1 6.65 x 10-1 5.0 x 10-2 4.13 x 10-1 3.30 x 10-1 1.07 x 10-1
23.27 296.42 1.90 x 10-1 6.84 x 10-1 5.0 x 10-2 4.22 x 10-1 3.46 x 10-1 1.09 x 10-1
23.46 295.61 1.90 x 10-1 6.46 x 10-1 5.0 x 10-2 4.05 x 10-1 3.14 x 10-1 1.05 x 10-1
25.97 299.12 1.90 x 10-1 6.27 x 10-1 5.0 x 10-2 3.97 x 10-1 2.99 x 10-1 1.03 x 10-1
26.68 299.83 1.90 x 10-1 7.03 x 10-1 5.0 x 10-2 4.31 x 10-1 3.63 x 10-1 1.12 x 10-1
28.43 301.58 1.90 x 10-1 6.08 x 10-1 5.0 x 10-2 3.89 x 10-1 2.84 x 10-1 1.01 x 10-1
31.96 305.11 1.90 x 10-1 5.89 x 10-1 5.0 x 10-2 3.82 x 10-1 2.70 x 10-1 9.9 x 10-2
33.53 306.68 1.90 x 10-1 7.22 x 10-1 5.0 x 10-2 4.41 x 10-1 3.81 x 10-1 1.14 x 10-1
35.87 309.02 1.90 x 10-1 5.70 x 10-1 5.0 x 10-2 3.75 x 10-1 2.56 x 10-1 9.7 x 10-2
40.32 313.47 1.90 x 10-1 5.51 x 10-1 5.0 x 10-2 3.68 x 10-1 2.43 x 10-1 9.5 x 10-2
44.35 317.5 1.90 x 10-1 5.32 x 10-1 5.0 x 10-2 3.61 x 10-1 2.31 x 10-1 9.4 x 10-2
47.85 321.0 1.90 x 10-1 5.13 x 10-1 5.0 x 10-2 3.55 x 10-1 2.18 x 10-1 9.2 x 10-2
52.0 325.15 1.90 x 10-1 4.94 x 10-1 5.0 x 10-2 3.49 x 10-1 2.07 x 10-1 9.0 x 10-2
21.82 294.97 3.80 x 10-1 4.99 x 10-1 5.0 x 10-2 6.39 x 10-1 1.91 x 10-1 8.3 x 10-2
22.83 295.98 3.80 x 10-1 5.13 x 10-1 5.0 x 10-2 6.47 x 10-1 1.99 x 10-1 8.4 x 10-2
25.58 298.73 3.80 x 10-1 4.85 x 10-1 5.0 x 10-2 6.32 x 10-1 1.83 x 10-1 8.2 x 10-2
27.23 300.38 3.80 x 10-1 5.27 x 10-1 5.0 x 10-2 6.55 x 10-1 2.07 x 10-1 8.5 x 10-2
31.98 305.13 3.80 x 10-1 4.70 x 10-1 5.0 x 10-2 6.24 x 10-1 1.76 x 10-1 8.1 x 10-2
34.07 307.22 3.80 x 10-1 5.42 x 10-1 5.0 x 10-2 6.63 x 10-1 2.15 x 10-1 8.6 x 10-2
36.02 309.17 3.80 x 10-1 3.99 x 10-1 5.0 x 10-2 5.90 x 10-1 1.41 x 10-1 7.6 x 10-2
40.76 313.91 3.80 x 10-1 4.56 x 10-1 5.0 x 10-2 6.17 x 10-1 1.69 x 10-1 8.0 x 10-2
42.33 315.48 3.80 x 10-1 4.13 x 10-1 5.0 x 10-2 5.96 x 10-1 1.48 x 10-1 7.7 x 10-2
53.35 326.5 3.80 x 10-1 4.28 x 10-1 5.0 x 10-2 6.03 x 10-1 1.55 x 10-1 7.8 x 10-2
10.48 283.63 9.0 x 10-2 6.88 x 10-1 1.00 x 10-1 2.08 x 10-1 3.62 x 10-1 2.27 x 10-1
10.72 283.87 9.0 x 10-2 4.86 x 10-1 1.00 x 10-1 1.69 x 10-1 2.07 x 10-1 1.84 x 10-1
11.45 284.6 9.0 x 10-2 5.06 x 10-1 1.00 x 10-1 1.72 x 10-1 2.20 x 10-1 1.88 x 10-1
11.57 284.72 9.0 x 10-2 6.68 x 10-1 1.00 x 10-1 2.03 x 10-1 3.43 x 10-1 2.22 x 10-1
11.98 285.13 9.0 x 10-2 5.27 x 10-1 1.00 x 10-1 1.75 x 10-1 2.34 x 10-1 1.91 x 10-1
12.04 285.19 9.0 x 10-2 6.48 x 10-1 1.00 x 10-1 1.98 x 10-1 3.26 x 10-1 2.17 x 10-1
12.27 285.42 9.0 x 10-2 6.28 x 10-1 1.00 x 10-1 1.94 x 10-1 3.09 x 10-1 2.12 x 10-1
12.27 285.42 9.0 x 10-2 5.47 x 10-1 1.00 x 10-1 1.79 x 10-1 2.47 x 10-1 1.95 x 10-1
12.41 285.56 9.0 x 10-2 6.07 x 10-1 1.00 x 10-1 1.90 x 10-1 2.92 x 10-1 2.08 x 10-1
12.44 285.59 9.0 x 10-2 5.67 x 10-1 1.00 x 10-1 1.82 x 10-1 2.62 x 10-1 1.99 x 10-1
12.53 285.68 9.0 x 10-2 5.87 x 10-1 1.00 x 10-1 1.85 x 10-1 2.77 x 10-1 2.03 x 10-1
22.11 295.26 1.80 x 10-1 6.12 x 10-1 1.00 x 10-1 3.63 x 10-1 2.81 x 10-1 1.98 x 10-1
22.28 295.43 1.80 x 10-1 6.30 x 10-1 1.00 x 10-1 3.69 x 10-1 2.95 x 10-1 2.02 x 10-1
23.87 297.02 1.80 x 10-1 6.48 x 10-1 1.00 x 10-1 3.76 x 10-1 3.09 x 10-1 2.06 x 10-1
25.23 298.38 1.80 x 10-1 5.94 x 10-1 1.00 x 10-1 3.56 x 10-1 2.68 x 10-1 1.95 x 10-1
26.13 299.28 1.80 x 10-1 6.66 x 10-1 1.00 x 10-1 3.84 x 10-1 3.23 x 10-1 2.10 x 10-1
27.75 300.9 1.80 x 10-1 5.76 x 10-1 1.00 x 10-1 3.50 x 10-1 2.56 x 10-1 1.91 x 10-1
31.53 304.68 1.80 x 10-1 5.58 x 10-1 1.00 x 10-1 3.44 x 10-1 2.43 x 10-1 1.88 x 10-1
34.32 307.47 1.80 x 10-1 5.40 x 10-1 1.00 x 10-1 3.38 x 10-1 2.31 x 10-1 1.85 x 10-1
37.97 311.12 1.80 x 10-1 5.22 x 10-1 1.00 x 10-1 3.33 x 10-1 2.20 x 10-1 1.82 x 10-1
39.38 312.53 1.80 x 10-1 5.04 x 10-1 1.00 x 10-1 3.27 x 10-1 2.09 x 10-1 1.79 x 10-1
43.75 316.9 1.80 x 10-1 4.86 x 10-1 1.00 x 10-1 3.22 x 10-1 1.98 x 10-1 1.76 x 10-1
47.9 321.05 1.80 x 10-1 4.68 x 10-1 1.00 x 10-1 3.17 x 10-1 1.88 x 10-1 1.73 x 10-1
49.85 323.0 1.80 x 10-1 4.50 x 10-1 1.00 x 10-1 3.12 x 10-1 1.78 x 10-1 1.70 x 10-1
54.3 327.45 1.80 x 10-1 4.32 x 10-1 1.00 x 10-1 3.07 x 10-1 1.68 x 10-1 1.68 x 10-1
21.92 295.07 3.60 x 10-1 4.99 x 10-1 1.00 x 10-1 5.98 x 10-1 1.89 x 10-1 1.64 x 10-1
22.23 295.38 3.60 x 10-1 4.72 x 10-1 1.00 x 10-1 5.85 x 10-1 1.75 x 10-1 1.60 x 10-1
23.16 296.31 3.60 x 10-1 4.86 x 10-1 1.00 x 10-1 5.92 x 10-1 1.82 x 10-1 1.62 x 10-1
26.47 299.62 3.60 x 10-1 4.59 x 10-1 1.00 x 10-1 5.79 x 10-1 1.68 x 10-1 1.58 x 10-1
35.37 308.52 3.60 x 10-1 4.46 x 10-1 1.00 x 10-1 5.73 x 10-1 1.62 x 10-1 1.56 x 10-1
42.9 316.05 3.60 x 10-1 4.32 x 10-1 1.00 x 10-1 5.67 x 10-1 1.55 x 10-1 1.55 x 10-1
49.35 322.5 3.60 x 10-1 3.78 x 10-1 1.00 x 10-1 5.44 x 10-1 1.30 x 10-1 1.49 x 10-1
52.25 325.4 3.60 x 10-1 4.19 x 10-1 1.00 x 10-1 5.61 x 10-1 1.49 x 10-1 1.53 x 10-1
52.95 326.1 3.60 x 10-1 3.91 x 10-1 1.00 x 10-1 5.49 x 10-1 1.36 x 10-1 1.50 x 10-1
61.2 334.35 3.60 x 10-1 4.05 x 10-1 1.00 x 10-1 5.55 x 10-1 1.42 x 10-1 1.52 x 10-1
14.1 287.25 4.0 x 10-2 7.03 x 10-1 2.00 x 10-1 9.1 x 10-2 3.66 x 10-1 4.49 x 10-1
15.75 288.9 4.0 x 10-2 6.84 x 10-1 2.00 x 10-1 8.9 x 10-2 3.48 x 10-1 4.39 x 10-1
16.1 289.25 4.0 x 10-2 4.94 x 10-1 2.00 x 10-1 7.4 x 10-2 2.07 x 10-1 3.63 x 10-1
17.03 290.18 4.0 x 10-2 6.65 x 10-1 2.00 x 10-1 8.7 x 10-2 3.32 x 10-1 4.30 x 10-1
17.05 290.2 4.0 x 10-2 5.13 x 10-1 2.00 x 10-1 7.5 x 10-2 2.20 x 10-1 3.69 x 10-1
17.4 290.55 4.0 x 10-2 5.32 x 10-1 2.00 x 10-1 7.6 x 10-2 2.32 x 10-1 3.76 x 10-1
17.81 290.96 4.0 x 10-2 6.46 x 10-1 2.00 x 10-1 8.6 x 10-2 3.16 x 10-1 4.21 x 10-1
17.95 291.1 4.0 x 10-2 5.51 x 10-1 2.00 x 10-1 7.8 x 10-2 2.44 x 10-1 3.83 x 10-1
18.5 291.65 4.0 x 10-2 5.89 x 10-1 2.00 x 10-1 8.1 x 10-2 2.71 x 10-1 3.97 x 10-1
18.55 291.7 4.0 x 10-2 5.70 x 10-1 2.00 x 10-1 7.9 x 10-2 2.58 x 10-1 3.90 x 10-1
18.55 291.7 4.0 x 10-2 6.27 x 10-1 2.00 x 10-1 8.4 x 10-2 3.00 x 10-1 4.13 x 10-1
18.62 291.77 4.0 x 10-2 6.08 x 10-1 2.00 x 10-1 8.2 x 10-2 2.86 x 10-1 4.05 x 10-1
11.6 284.75 8.0 x 10-2 6.30 x 10-1 2.00 x 10-1 1.65 x 10-1 2.96 x 10-1 4.05 x 10-1
11.86 285.01 8.0 x 10-2 4.68 x 10-1 2.00 x 10-1 1.41 x 10-1 1.88 x 10-1 3.48 x 10-1
12.3 285.45 8.0 x 10-2 4.86 x 10-1 2.00 x 10-1 1.43 x 10-1 1.99 x 10-1 3.53 x 10-1
12.42 285.57 8.0 x 10-2 6.12 x 10-1 2.00 x 10-1 1.62 x 10-1 2.82 x 10-1 3.98 x 10-1
12.75 285.9 8.0 x 10-2 5.04 x 10-1 2.00 x 10-1 1.46 x 10-1 2.09 x 10-1 3.59 x 10-1
12.91 286.06 8.0 x 10-2 5.22 x 10-1 2.00 x 10-1 1.48 x 10-1 2.21 x 10-1 3.65 x 10-1
12.97 296.12 8.0 x 10-2 5.94 x 10-1 2.00 x 10-1 1.59 x 10-1 2.69 x 10-1 3.91 x 10-1
13.05 286.2 8.0 x 10-2 5.40 x 10-1 2.00 x 10-1 1.51 x 10-1 2.32 x 10-1 3.71 x 10-1
13.15 286.3 8.0 x 10-2 5.58 x 10-1 2.00 x 10-1 1.54 x 10-1 2.44 x 10-1 3.77 x 10-1
13.23 286.38 8.0 x 10-2 5.76 x 10-1 2.00 x 10-1 1.56 x 10-1 2.56 x 10-1 3.84 x 10-1
19.2 292.35 1.60 x 10-1 5.60 x 10-1 2.00 x 10-1 2.95 x 10-1 2.35 x 10-1 3.63 x 10-1
19.65 292.8 1.60 x 10-1 5.44 x 10-1 2.00 x 10-1 2.91 x 10-1 2.25 x 10-1 3.57 x 10-1
21.22 294.37 1.60 x 10-1 5.76 x 10-1 2.00 x 10-1 2.99 x 10-1 2.46 x 10-1 3.68 x 10-1
23.1 296.25 1.60 x 10-1 5.12 x 10-1 2.00 x 10-1 2.83 x 10-1 2.06 x 10-1 3.47 x 10-1
25.61 298.76 1.60 x 10-1 4.96 x 10-1 2.00 x 10-1 2.79 x 10-1 1.97 x 10-1 3.42 x 10-1
26.6 299.75 1.60 x 10-1 4.80 x 10-1 2.00 x 10-1 2.75 x 10-1 1.88 x 10-1 3.38 x 10-1
26.85 300.0 1.60 x 10-1 4.64 x 10-1 2.00 x 10-1 2.71 x 10-1 1.79 x 10-1 3.33 x 10-1
27.8 300.95 1.60 x 10-1 4.48 x 10-1 2.00 x 10-1 2.67 x 10-1 1.71 x 10-1 3.29 x 10-1
28.02 301.17 1.60 x 10-1 6.08 x 10-1 2.00 x 10-1 3.09 x 10-1 2.67 x 10-1 3.79 x 10-1
32.81 305.96 1.60 x 10-1 4.32 x 10-1 2.00 x 10-1 2.64 x 10-1 1.62 x 10-1 3.25 x 10-1
34.71 307.86 1.60 x 10-1 4.16 x 10-1 2.00 x 10-1 2.61 x 10-1 1.54 x 10-1 3.20 x 10-1
22.5 295.65 3.20 x 10-1 4.32 x 10-1 2.00 x 10-1 4.92 x 10-1 1.51 x 10-1 3.03 x 10-1
23.71 296.86 3.20 x 10-1 4.20 x 10-1 2.00 x 10-1 4.88 x 10-1 1.46 x 10-1 3.00 x 10-1
26.9 300.05 3.20 x 10-1 4.08 x 10-1 2.00 x 10-1 4.83 x 10-1 1.41 x 10-1 2.97 x 10-1
31.12 304.27 3.20 x 10-1 4.44 x 10-1 2.00 x 10-1 4.97 x 10-1 1.57 x 10-1 3.05 x 10-1
35.0 308.15 3.20 x 10-1 3.96 x 10-1 2.00 x 10-1 4.79 x 10-1 1.35 x 10-1 2.95 x 10-1
35.5 308.65 3.20 x 10-1 4.56 x 10-1 2.00 x 10-1 5.02 x 10-1 1.63 x 10-1 3.08 x 10-1
45.55 318.7 3.20 x 10-1 3.84 x 10-1 2.00 x 10-1 4.75 x 10-1 1.30 x 10-1 2.92 x 10-1
51.3 324.45 3.20 x 10-1 3.36 x 10-1 2.00 x 10-1 4.58 x 10-1 1.10 x 10-1 2.82 x 10-1
54.25 327.4 3.20 x 10-1 3.48 x 10-1 2.00 x 10-1 4.63 x 10-1 1.15 x 10-1 2.84 x 10-1
56.4 329.55 3.20 x 10-1 3.72 x 10-1 2.00 x 10-1 4.71 x 10-1 1.25 x 10-1 2.89 x 10-1
60.1 333.25 3.20 x 10-1 3.60 x 10-1 2.00 x 10-1 4.66 x 10-1 1.20 x 10-1 2.87 x 10-1
70.5 343.7 3.20 x 10-1 3.24 x 10-1 2.00 x 10-1 4.55 x 10-1 1.05 x 10-1 2.79 x 10-1
23.21 296.36 2.10 x 10-1 4.29 x 10-1 3.00 x 10-1 3.25 x 10-1 1.51 x 10-1 4.56 x 10-1
24.68 297.83 2.10 x 10-1 4.16 x 10-1 3.00 x 10-1 3.21 x 10-1 1.45 x 10-1 4.52 x 10-1
24.95 298.1 2.10 x 10-1 4.41 x 10-1 3.00 x 10-1 3.28 x 10-1 1.57 x 10-1 4.60 x 10-1
27.35 300.5 2.10 x 10-1 4.04 x 10-1 3.00 x 10-1 3.18 x 10-1 1.40 x 10-1 4.47 x 10-1
30.24 303.39 2.10 x 10-1 3.92 x 10-1 3.00 x 10-1 3.16 x 10-1 1.34 x 10-1 4.43 x 10-1
31.86 305.01 2.10 x 10-1 4.66 x 10-1 3.00 x 10-1 3.34 x 10-1 1.69 x 10-1 4.69 x 10-1
33.42 306.57 2.10 x 10-1 3.80 x 10-1 3.00 x 10-1 3.13 x 10-1 1.29 x 10-1 4.39 x 10-1
35.97 309.12 2.10 x 10-1 3.68 x 10-1 3.00 x 10-1 3.10 x 10-1 1.24 x 10-1 4.35 x 10-1
36.3 309.45 2.10 x 10-1 4.9 x 10-2 3.00 x 10-1 2.51 x 10-1 1.3 x 10-2 3.53 x 10-1
36.35 309.5 2.10 x 10-1 9.8 x 10-2 3.00 x 10-1 2.59 x 10-1 2.8 x 10-2 3.63 x 10-1
36.72 309.87 2.10 x 10-1 1.47 x 10-1 3.00 x 10-1 2.67 x 10-1 4.2 x 10-2 3.75 x 10-1
36.94 310.09 2.10 x 10-1 1.96 x 10-1 3.00 x 10-1 2.75 x 10-1 5.9 x 10-2 3.87 x 10-1
37.2 310.35 2.10 x 10-1 3.55 x 10-1 3.00 x 10-1 3.07 x 10-1 1.18 x 10-1 4.32 x 10-1
37.84 310.99 2.10 x 10-1 2.45 x 10-1 3.00 x 10-1 2.84 x 10-1 7.6 x 10-2 3.99 x 10-1
38.1 311.25 2.10 x 10-1 3.43 x 10-1 3.00 x 10-1 3.04 x 10-1 1.13 x 10-1 4.28 x 10-1
39.27 312.42 2.10 x 10-1 3.19 x 10-1 3.00 x 10-1 2.99 x 10-1 1.04 x 10-1 4.20 x 10-1
39.91 313.06 2.10 x 10-1 2.94 x 10-1 3.00 x 10-1 2.94 x 10-1 9.4 x 10-2 4.13 x 10-1
23.62 296.77 2.80 x 10-1 3.67 x 10-1 3.00 x 10-1 4.02 x 10-1 1.20 x 10-1 4.23 x 10-1
28.14 301.29 2.80 x 10-1 3.57 x 10-1 3.00 x 10-1 3.99 x 10-1 1.15 x 10-1 4.20 x 10-1
34.68 307.83 2.80 x 10-1 3.47 x 10-1 3.00 x 10-1 3.96 x 10-1 1.12 x 10-1 4.17 x 10-1
36.7 309.85 2.80 x 10-1 3.99 x 10-1 3.00 x 10-1 4.11 x 10-1 1.34 x 10-1 4.33 x 10-1
39.66 312.81 2.80 x 10-1 8.4 x 10-2 3.00 x 10-1 3.34 x 10-1 2.3 x 10-2 3.52 x 10-1
39.8 312.95 2.80 x 10-1 4.2 x 10-2 3.00 x 10-1 3.26 x 10-1 1.1 x 10-2 3.44 x 10-1
41.18 314.33 2.80 x 10-1 1.26 x 10-1 3.00 x 10-1 3.43 x 10-1 3.5 x 10-2 3.61 x 10-1
41.2 314.35 2.80 x 10-1 3.36 x 10-1 3.00 x 10-1 3.93 x 10-1 1.07 x 10-1 4.14 x 10-1
41.65 314.8 2.80 x 10-1 1.68 x 10-1 3.00 x 10-1 3.52 x 10-1 4.8 x 10-2 3.71 x 10-1
42.7 315.85 2.80 x 10-1 2.10 x 10-1 3.00 x 10-1 3.61 x 10-1 6.2 x 10-2 3.81 x 10-1
44.8 317.95 2.80 x 10-1 2.52 x 10-1 3.00 x 10-1 3.71 x 10-1 7.6 x 10-2 3.91 x 10-1
45.75 318.9 2.80 x 10-1 3.25 x 10-1 3.00 x 10-1 3.90 x 10-1 1.03 x 10-1 4.11 x 10-1
46.25 319.4 2.80 x 10-1 2.73 x 10-1 3.00 x 10-1 3.76 x 10-1 8.4 x 10-2 3.97 x 10-1
48.15 321.3 2.80 x 10-1 2.94 x 10-1 3.00 x 10-1 3.82 x 10-1 9.1 x 10-2 4.02 x 10-1
48.4 321.55 2.80 x 10-1 3.15 x 10-1 3.00 x 10-1 3.87 x 10-1 9.9 x 10-2 4.08 x 10-1
49.25 322.4 2.80 x 10-1 3.04 x 10-1 3.00 x 10-1 3.85 x 10-1 9.5 x 10-2 4.05 x 10-1
13.13 286.28 6.0 x 10-2 3.24 x 10-1 4.00 x 10-1 8.8 x 10-2 1.08 x 10-1 5.75 x 10-1
14.62 287.77 6.0 x 10-2 4.86 x 10-1 4.00 x 10-1 9.9 x 10-2 1.84 x 10-1 6.52 x 10-1
15.67 288.82 6.0 x 10-2 3.51 x 10-1 4.00 x 10-1 9.0 x 10-2 1.19 x 10-1 5.87 x 10-1
17.09 290.24 6.0 x 10-2 4.73 x 10-1 4.00 x 10-1 9.8 x 10-2 1.77 x 10-1 6.45 x 10-1
17.27 290.42 6.0 x 10-2 3.78 x 10-1 4.00 x 10-1 9.1 x 10-2 1.31 x 10-1 5.99 x 10-1
17.83 290.98 6.0 x 10-2 3.91 x 10-1 4.00 x 10-1 9.2 x 10-2 1.37 x 10-1 6.05 x 10-1
18.17 291.32 6.0 x 10-2 4.05 x 10-1 4.00 x 10-1 9.3 x 10-2 1.44 x 10-1 6.11 x 10-1
18.17 291.32 6.0 x 10-2 4.59 x 10-1 4.00 x 10-1 9.7 x 10-2 1.70 x 10-1 6.38 x 10-1
18.32 291.47 6.0 x 10-2 4.46 x 10-1 4.00 x 10-1 9.6 x 10-2 1.63 x 10-1 6.31 x 10-1
18.35 291.5 6.0 x 10-2 4.19 x 10-1 4.00 x 10-1 9.4 x 10-2 1.50 x 10-1 6.18 x 10-1
18.35 291.5 6.0 x 10-2 4.32 x 10-1 4.00 x 10-1 9.5 x 10-2 1.56 x 10-1 6.25 x 10-1
10.21 283.36 1.20 x 10-1 4.20 x 10-1 4.00 x 10-1 1.84 x 10-1 1.47 x 10-1 6.03 x 10-1
11.18 284.33 1.20 x 10-1 3.12 x 10-1 4.00 x 10-1 1.70 x 10-1 1.01 x 10-1 5.57 x 10-1
11.71 284.86 1.20 x 10-1 4.08 x 10-1 4.00 x 10-1 1.82 x 10-1 1.41 x 10-1 5.97 x 10-1
11.78 284.93 1.20 x 10-1 3.24 x 10-1 4.00 x 10-1 1.71 x 10-1 1.05 x 10-1 5.62 x 10-1
12.16 285.31 1.20 x 10-1 3.36 x 10-1 4.00 x 10-1 1.73 x 10-1 1.10 x 10-1 5.67 x 10-1
12.3 285.45 1.20 x 10-1 3.96 x 10-1 4.00 x 10-1 1.80 x 10-1 1.36 x 10-1 5.92 x 10-1
12.32 285.47 1.20 x 10-1 3.60 x 10-1 4.00 x 10-1 1.76 x 10-1 1.20 x 10-1 5.76 x 10-1
12.39 285.54 1.20 x 10-1 3.48 x 10-1 4.00 x 10-1 1.74 x 10-1 1.15 x 10-1 5.72 x 10-1
12.51 285.66 1.20 x 10-1 3.84 x 10-1 4.00 x 10-1 1.79 x 10-1 1.30 x 10-1 5.87 x 10-1
12.52 285.67 1.20 x 10-1 3.72 x 10-1 4.00 x 10-1 1.77 x 10-1 1.25 x 10-1 5.82 x 10-1
23.89 297.04 2.40 x 10-1 3.15 x 10-1 4.00 x 10-1 3.25 x 10-1 9.7 x 10-2 5.33 x 10-1
23.98 297.13 2.40 x 10-1 3.24 x 10-1 4.00 x 10-1 3.27 x 10-1 1.01 x 10-1 5.36 x 10-1
27.01 300.16 2.40 x 10-1 3.06 x 10-1 4.00 x 10-1 3.23 x 10-1 9.4 x 10-2 5.30 x 10-1
28.21 301.36 2.40 x 10-1 3.33 x 10-1 4.00 x 10-1 3.29 x 10-1 1.04 x 10-1 5.40 x 10-1
31.55 304.7 2.40 x 10-1 2.97 x 10-1 4.00 x 10-1 3.21 x 10-1 9.1 x 10-2 5.27 x 10-1
35.65 308.8 2.40 x 10-1 2.88 x 10-1 4.00 x 10-1 3.19 x 10-1 8.7 x 10-2 5.24 x 10-1
37.72 310.87 2.40 x 10-1 2.79 x 10-1 4.00 x 10-1 3.18 x 10-1 8.4 x 10-2 5.20 x 10-1
39.1 312.25 2.40 x 10-1 2.70 x 10-1 4.00 x 10-1 3.16 x 10-1 8.1 x 10-2 5.17 x 10-1
39.45 312.6 2.40 x 10-1 2.61 x 10-1 4.00 x 10-1 3.14 x 10-1 7.8 x 10-2 5.14 x 10-1
47.0 320.15 2.40 x 10-1 2.52 x 10-1 4.00 x 10-1 3.12 x 10-1 7.5 x 10-2 5.11 x 10-1
15.49 288.64 5.0 x 10-2 2.81 x 10-1 5.00 x 10-1 6.9 x 10-2 8.8 x 10-2 6.75 x 10-1
16.86 290.01 5.0 x 10-2 2.92 x 10-1 5.00 x 10-1 6.9 x 10-2 9.2 x 10-2 6.81 x 10-1
18.09 291.24 5.0 x 10-2 4.05 x 10-1 5.00 x 10-1 7.5 x 10-2 1.38 x 10-1 7.38 x 10-1
18.19 291.34 5.0 x 10-2 3.04 x 10-1 5.00 x 10-1 7.0 x 10-2 9.7 x 10-2 6.86 x 10-1
18.99 292.14 5.0 x 10-2 3.15 x 10-1 5.00 x 10-1 7.0 x 10-2 1.01 x 10-1 6.91 x 10-1
19.1 292.25 5.0 x 10-2 3.26 x 10-1 5.00 x 10-1 7.1 x 10-2 1.05 x 10-1 6.97 x 10-1
19.1 292.25 5.0 x 10-2 3.94 x 10-1 5.00 x 10-1 7.4 x 10-2 1.34 x 10-1 7.31 x 10-1
20.46 293.61 5.0 x 10-2 3.37 x 10-1 5.00 x 10-1 7.1 x 10-2 1.10 x 10-1 7.02 x 10-1
20.51 293.66 5.0 x 10-2 3.83 x 10-1 5.00 x 10-1 7.4 x 10-2 1.29 x 10-1 7.25 x 10-1
20.56 293.71 5.0 x 10-2 3.49 x 10-1 5.00 x 10-1 7.2 x 10-2 1.14 x 10-1 7.08 x 10-1
20.62 293.77 5.0 x 10-2 3.60 x 10-1 5.00 x 10-1 7.2 x 10-2 1.19 x 10-1 7.14 x 10-1
20.82 293.97 5.0 x 10-2 3.71 x 10-1 5.00 x 10-1 7.3 x 10-2 1.24 x 10-1 7.19 x 10-1
12.11 285.26 1.00 x 10-1 2.60 x 10-1 5.00 x 10-1 1.33 x 10-1 7.9 x 10-2 6.53 x 10-1
13.11 286.26 1.00 x 10-1 2.70 x 10-1 5.00 x 10-1 1.34 x 10-1 8.2 x 10-2 6.58 x 10-1
13.62 286.77 1.00 x 10-1 3.50 x 10-1 5.00 x 10-1 1.41 x 10-1 1.13 x 10-1 6.95 x 10-1
13.86 287.01 1.00 x 10-1 2.80 x 10-1 5.00 x 10-1 1.35 x 10-1 8.6 x 10-2 6.62 x 10-1
14.4 287.55 1.00 x 10-1 2.90 x 10-1 5.00 x 10-1 1.35 x 10-1 9.0 x 10-2 6.67 x 10-1
14.58 287.73 1.00 x 10-1 3.40 x 10-1 5.00 x 10-1 1.40 x 10-1 1.09 x 10-1 6.90 x 10-1
14.71 287.86 1.00 x 10-1 3.00 x 10-1 5.00 x 10-1 1.37 x 10-1 9.3 x 10-2 6.71 x 10-1
14.79 287.94 1.00 x 10-1 3.10 x 10-1 5.00 x 10-1 1.37 x 10-1 9.7 x 10-2 6.76 x 10-1
14.88 288.03 1.00 x 10-1 3.20 x 10-1 5.00 x 10-1 1.38 x 10-1 1.01 x 10-1 6.81 x 10-1
14.91 288.06 1.00 x 10-1 3.30 x 10-1 5.00 x 10-1 1.39 x 10-1 1.05 x 10-1 6.85 x 10-1
19.9 293.05 2.00 x 10-1 2.63 x 10-1 5.00 x 10-1 2.57 x 10-1 7.7 x 10-2 6.31 x 10-1
20.51 293.66 2.00 x 10-1 2.55 x 10-1 5.00 x 10-1 2.56 x 10-1 7.4 x 10-2 6.28 x 10-1
20.91 294.06 2.00 x 10-1 2.47 x 10-1 5.00 x 10-1 2.54 x 10-1 7.2 x 10-2 6.25 x 10-1
21.15 294.3 2.00 x 10-1 2.70 x 10-1 5.00 x 10-1 2.58 x 10-1 7.9 x 10-2 6.35 x 10-1
21.65 294.8 2.00 x 10-1 2.77 x 10-1 5.00 x 10-1 2.59 x 10-1 8.2 x 10-2 6.38 x 10-1
24.21 297.36 2.00 x 10-1 2.25 x 10-1 5.00 x 10-1 2.51 x 10-1 6.4 x 10-2 6.17 x 10-1
25.36 298.51 2.00 x 10-1 2.17 x 10-1 5.00 x 10-1 2.49 x 10-1 6.2 x 10-2 6.14 x 10-1
25.52 298.67 2.00 x 10-1 2.10 x 10-1 5.00 x 10-1 2.49 x 10-1 5.9 x 10-2 6.11 x 10-1
12.35 285.5 6.4 x 10-2 6.42 x 10-1 5.0 x 10-2 1.47 x 10-1 3.35 x 10-1 1.13 x 10-1
12.51 285.66 8.0 x 10-2 6.31 x 10-1 5.0 x 10-2 1.79 x 10-1 3.22 x 10-1 1.10 x 10-1
12.76 285.91 5.6 x 10-2 6.48 x 10-1 5.0 x 10-2 1.30 x 10-1 3.42 x 10-1 1.14 x 10-1
13.93 287.08 4.6 x 10-2 6.55 x 10-1 5.0 x 10-2 1.08 x 10-1 3.51 x 10-1 1.15 x 10-1
15.35 288.5 8.6 x 10-2 6.26 x 10-1 5.0 x 10-2 1.91 x 10-1 3.17 x 10-1 1.09 x 10-1
15.75 288.9 3.7 x 10-2 6.62 x 10-1 5.0 x 10-2 8.8 x 10-2 3.60 x 10-1 1.17 x 10-1
17.97 291.12 2.8 x 10-2 6.68 x 10-1 5.0 x 10-2 6.8 x 10-2 3.68 x 10-1 1.19 x 10-1
19.22 292.37 9.5 x 10-2 6.20 x 10-1 5.0 x 10-2 2.08 x 10-1 3.10 x 10-1 1.08 x 10-1
20.63 293.78 2.0 x 10-2 6.74 x 10-1 5.0 x 10-2 4.9 x 10-2 3.76 x 10-1 1.20 x 10-1
23.51 296.66 1.1 x 10-2 6.81 x 10-1 5.0 x 10-2 2.7 x 10-2 3.86 x 10-1 1.22 x 10-1
26.28 299.43 1.15 x 10-1 6.05 x 10-1 5.0 x 10-2 2.45 x 10-1 2.94 x 10-1 1.05 x 10-1
12.33 285.48 6.8 x 10-2 6.03 x 10-1 1.00 x 10-1 1.45 x 10-1 2.92 x 10-1 2.09 x 10-1
12.47 285.62 8.3 x 10-2 5.92 x 10-1 1.00 x 10-1 1.73 x 10-1 2.82 x 10-1 2.05 x 10-1
12.53 285.68 9.0 x 10-2 5.87 x 10-1 1.00 x 10-1 1.86 x 10-1 2.77 x 10-1 2.03 x 10-1
14.81 287.96 4.5 x 10-2 6.20 x 10-1 1.00 x 10-1 9.9 x 10-2 3.10 x 10-1 2.16 x 10-1
15.09 288.24 1.09 x 10-1 5.74 x 10-1 1.00 x 10-1 2.20 x 10-1 2.64 x 10-1 1.98 x 10-1
19.88 293.03 2.4 x 10-2 6.35 x 10-1 1.00 x 10-1 5.4 x 10-2 3.27 x 10-1 2.23 x 10-1
22.67 295.82 1.35 x 10-1 5.55 x 10-1 1.00 x 10-1 2.64 x 10-1 2.47 x 10-1 1.92 x 10-1
11.95 285.1 7.0 x 10-2 5.29 x 10-1 2.00 x 10-1 1.31 x 10-1 2.26 x 10-1 3.69 x 10-1
12.26 285.41 6.1 x 10-2 5.36 x 10-1 2.00 x 10-1 1.16 x 10-1 2.32 x 10-1 3.73 x 10-1
12.45 285.6 7.9 x 10-2 5.23 x 10-1 2.00 x 10-1 1.47 x 10-1 2.21 x 10-1 3.65 x 10-1
12.47 285.62 8.1 x 10-2 5.21 x 10-1 2.00 x 10-1 1.50 x 10-1 2.20 x 10-1 3.64 x 10-1
13.09 286.24 6.0 x 10-2 5.36 x 10-1 2.00 x 10-1 1.14 x 10-1 2.32 x 10-1 3.74 x 10-1
14.21 287.36 5.0 x 10-2 5.44 x 10-1 2.00 x 10-1 9.6 x 10-2 2.39 x 10-1 3.78 x 10-1
17.15 290.3 3.7 x 10-2 5.53 x 10-1 2.00 x 10-1 7.2 x 10-2 2.46 x 10-1 3.84 x 10-1
21.67 294.82 1.9 x 10-2 5.66 x 10-1 2.00 x 10-1 3.8 x 10-2 2.58 x 10-1 3.93 x 10-1
23.92 297.07 9.8 x 10-2 5.09 x 10-1 2.00 x 10-1 1.78 x 10-1 2.11 x 10-1 3.57 x 10-1

(a) Critical opalescence.

Table 3. Solubility temperatures of the two liquid phases
T (°C) T (K) w1 w2 w3 x1 x2 x3
116.1 389.3 9.5 x 10-2 7.27 x 10-1 5.0 x 10-2 2.36 x 10-1 4.11 x 10-1 1.22 x 10-1
116.4 389.6 9.5 x 10-2 7.91 x 10-1 5.0 x 10-2 2.56 x 10-1 4.86 x 10-1 1.33 x 10-1
119.5 392.7 9.5 x 10-2 7.48 x 10-1 5.0 x 10-2 2.42 x 10-1 4.35 x 10-1 1.25 x 10-1
120.8 394.0 9.5 x 10-2 7.70 x 10-1 5.0 x 10-2 2.49 x 10-1 4.60 x 10-1 1.29 x 10-1
127.5 400.7 9.5 x 10-2 7.06 x 10-1 5.0 x 10-2 2.30 x 10-1 3.89 x 10-1 1.19 x 10-1
127.5 400.7 9.5 x 10-2 6.84 x 10-1 5.0 x 10-2 2.24 x 10-1 3.68 x 10-1 1.16 x 10-1
128.8 402.0 9.5 x 10-2 6.62 x 10-1 5.0 x 10-2 2.19 x 10-1 3.47 x 10-1 1.13 x 10-1
132.7 405.9 9.5 x 10-2 6.41 x 10-1 5.0 x 10-2 2.13 x 10-1 3.28 x 10-1 1.10 x 10-1
135.2 408.4 9.5 x 10-2 6.20 x 10-1 5.0 x 10-2 2.08 x 10-1 3.10 x 10-1 1.08 x 10-1
140.4 413.6 9.5 x 10-2 5.98 x 10-1 5.0 x 10-2 2.04 x 10-1 2.92 x 10-1 1.05 x 10-1
72.7 345.9 1.90 x 10-1 7.22 x 10-1 5.0 x 10-2 4.41 x 10-1 3.81 x 10-1 1.14 x 10-1
76.2 349.4 1.90 x 10-1 7.03 x 10-1 5.0 x 10-2 4.31 x 10-1 3.63 x 10-1 1.12 x 10-1
78.8 352.0 1.90 x 10-1 6.84 x 10-1 5.0 x 10-2 4.22 x 10-1 3.46 x 10-1 1.09 x 10-1
81.3 354.5 1.90 x 10-1 6.65 x 10-1 5.0 x 10-2 4.13 x 10-1 3.30 x 10-1 1.07 x 10-1
81.5 354.7 1.90 x 10-1 6.46 x 10-1 5.0 x 10-2 4.05 x 10-1 3.14 x 10-1 1.05 x 10-1
82.4 355.6 1.90 x 10-1 6.27 x 10-1 5.0 x 10-2 3.97 x 10-1 2.99 x 10-1 1.03 x 10-1
85.7 358.9 1.90 x 10-1 6.08 x 10-1 5.0 x 10-2 3.89 x 10-1 2.84 x 10-1 1.01 x 10-1
88.8 362.0 1.90 x 10-1 5.89 x 10-1 5.0 x 10-2 3.82 x 10-1 2.70 x 10-1 9.9 x 10-2
91.5 364.7 1.90 x 10-1 5.70 x 10-1 5.0 x 10-2 3.75 x 10-1 2.56 x 10-1 9.7 x 10-2
93.8 367.0 1.90 x 10-1 5.51 x 10-1 5.0 x 10-2 3.68 x 10-1 2.43 x 10-1 9.5 x 10-2
98.3 371.5 1.90 x 10-1 5.32 x 10-1 5.0 x 10-2 3.61 x 10-1 2.31 x 10-1 9.4 x 10-2
105.2 378.4 1.90 x 10-1 5.13 x 10-1 5.0 x 10-2 3.55 x 10-1 2.18 x 10-1 9.2 x 10-2
110.9 384.1 1.90 x 10-1 4.94 x 10-1 5.0 x 10-2 3.49 x 10-1 2.07 x 10-1 9.0 x 10-2
34.07 307.22 3.80 x 10-1 5.41 x 10-1 5.0 x 10-2 6.63 x 10-1 2.10 x 10-1 8.6 x 10-2
35.02 308.17 3.80 x 10-1 5.27 x 10-1 5.0 x 10-2 6.55 x 10-1 2.07 x 10-1 8.5 x 10-2
36.53 309.68 3.80 x 10-1 5.13 x 10-1 5.0 x 10-2 6.47 x 10-1 1.99 x 10-1 8.4 x 10-2
38.07 311.22 3.80 x 10-1 4.99 x 10-1 5.0 x 10-2 6.39 x 10-1 1.91 x 10-1 8.3 x 10-2
40.45 313.6 3.80 x 10-1 4.85 x 10-1 5.0 x 10-2 6.32 x 10-1 1.84 x 10-1 8.2 x 10-2
43.6 316.75 3.80 x 10-1 4.56 x 10-1 5.0 x 10-2 6.17 x 10-1 1.69 x 10-1 8.0 x 10-2
47.5 320.65 3.80 x 10-1 4.70 x 10-1 5.0 x 10-2 6.24 x 10-1 1.76 x 10-1 8.1 x 10-2
47.85 321.0 3.80 x 10-1 4.42 x 10-1 5.0 x 10-2 6.10 x 10-1 1.62 x 10-1 7.9 x 10-2
55.0 328.15 3.80 x 10-1 4.28 x 10-1 5.0 x 10-2 6.03 x 10-1 1.55 x 10-1 7.8 x 10-2
57.7 330.85 3.80 x 10-1 4.13 x 10-1 5.0 x 10-2 5.96 x 10-1 1.48 x 10-1 7.7 x 10-2
60.8 333.95 3.80 x 10-1 3.99 x 10-1 5.0 x 10-2 5.90 x 10-1 1.41 x 10-1 7.6 x 10-2
92.3 365.5 1.80 x 10-1 6.66 x 10-1 1.00 x 10-1 3.84 x 10-1 3.23 x 10-1 2.10 x 10-1
95.2 368.4 1.80 x 10-1 6.48 x 10-1 1.00 x 10-1 3.76 x 10-1 3.09 x 10-1 2.06 x 10-1
98.1 371.3 1.80 x 10-1 6.30 x 10-1 1.00 x 10-1 3.69 x 10-1 2.95 x 10-1 2.02 x 10-1
105.2 378.4 1.80 x 10-1 5.94 x 10-1 1.00 x 10-1 3.56 x 10-1 2.68 x 10-1 1.95 x 10-1
109.1 382.3 1.80 x 10-1 6.12 x 10-1 1.00 x 10-1 3.63 x 10-1 2.81 x 10-1 1.98 x 10-1
109.2 382.4 1.80 x 10-1 5.76 x 10-1 1.00 x 10-1 3.50 x 10-1 2.55 x 10-1 1.91 x 10-1
112.8 386.0 1.80 x 10-1 5.58 x 10-1 1.00 x 10-1 3.44 x 10-1 2.43 x 10-1 1.88 x 10-1
117.5 390.7 1.80 x 10-1 5.40 x 10-1 1.00 x 10-1 3.38 x 10-1 2.31 x 10-1 1.85 x 10-1
121.7 394.9 1.80 x 10-1 5.22 x 10-1 1.00 x 10-1 3.33 x 10-1 2.20 x 10-1 1.82 x 10-1
124.5 397.7 1.80 x 10-1 5.04 x 10-1 1.00 x 10-1 3.27 x 10-1 2.09 x 10-1 1.79 x 10-1
128.8 402.0 1.80 x 10-1 4.86 x 10-1 1.00 x 10-1 3.22 x 10-1 1.98 x 10-1 1.76 x 10-1
135.2 408.4 1.80 x 10-1 4.68 x 10-1 1.00 x 10-1 3.17 x 10-1 1.88 x 10-1 1.73 x 10-1
136.5 409.7 1.80 x 10-1 4.50 x 10-1 1.00 x 10-1 3.12 x 10-1 1.78 x 10-1 1.70 x 10-1
143.4 416.6 1.80 x 10-1 4.32 x 10-1 1.00 x 10-1 3.07 x 10-1 1.68 x 10-1 1.68 x 10-1
44.3 317.45 3.60 x 10-1 4.99 x 10-1 1.00 x 10-1 5.98 x 10-1 1.89 x 10-1 1.64 x 10-1
48.8 321.95 3.60 x 10-1 4.86 x 10-1 1.00 x 10-1 5.92 x 10-1 1.82 x 10-1 1.62 x 10-1
51.95 325.1 3.60 x 10-1 4.72 x 10-1 1.00 x 10-1 5.85 x 10-1 1.75 x 10-1 1.60 x 10-1
52.85 326.0 3.60 x 10-1 4.59 x 10-1 1.00 x 10-1 5.79 x 10-1 1.68 x 10-1 1.58 x 10-1
54.65 327.8 3.60 x 10-1 4.46 x 10-1 1.00 x 10-1 5.73 x 10-1 1.62 x 10-1 1.56 x 10-1
56.65 329.8 3.60 x 10-1 4.32 x 10-1 1.00 x 10-1 5.67 x 10-1 1.55 x 10-1 1.55 x 10-1
58.4 331.55 3.60 x 10-1 4.19 x 10-1 1.00 x 10-1 5.61 x 10-1 1.49 x 10-1 1.53 x 10-1
62.65 335.8 3.60 x 10-1 4.05 x 10-1 1.00 x 10-1 5.55 x 10-1 1.42 x 10-1 1.52 x 10-1
67.5 340.65 3.60 x 10-1 3.91 x 10-1 1.00 x 10-1 5.49 x 10-1 1.36 x 10-1 1.50 x 10-1
72.5 345.7 3.60 x 10-1 3.78 x 10-1 1.00 x 10-1 5.44 x 10-1 1.30 x 10-1 1.49 x 10-1
57.85 331.0 3.20 x 10-1 4.56 x 10-1 2.00 x 10-1 5.02 x 10-1 1.63 x 10-1 3.08 x 10-1
60.45 333.6 3.20 x 10-1 4.32 x 10-1 2.00 x 10-1 4.92 x 10-1 1.51 x 10-1 3.03 x 10-1
63.6 336.75 3.20 x 10-1 4.20 x 10-1 2.00 x 10-1 4.88 x 10-1 1.46 x 10-1 3.00 x 10-1
66.4 339.55 3.20 x 10-1 4.44 x 10-1 2.00 x 10-1 4.97 x 10-1 1.57 x 10-1 3.05 x 10-1
66.9 340.05 3.20 x 10-1 4.08 x 10-1 2.00 x 10-1 4.83 x 10-1 1.40 x 10-1 2.97 x 10-1
71.1 344.3 3.20 x 10-1 3.84 x 10-1 2.00 x 10-1 4.75 x 10-1 1.30 x 10-1 2.92 x 10-1
72.0 345.2 3.20 x 10-1 3.96 x 10-1 2.00 x 10-1 4.79 x 10-1 1.35 x 10-1 2.95 x 10-1
74.5 347.7 3.20 x 10-1 3.72 x 10-1 2.00 x 10-1 4.71 x 10-1 1.25 x 10-1 2.89 x 10-1
88.5 361.7 3.20 x 10-1 3.60 x 10-1 2.00 x 10-1 4.66 x 10-1 1.20 x 10-1 2.87 x 10-1
95.9 369.1 3.20 x 10-1 3.48 x 10-1 2.00 x 10-1 4.63 x 10-1 1.15 x 10-1 2.84 x 10-1
99.8 373.0 3.20 x 10-1 3.36 x 10-1 2.00 x 10-1 4.58 x 10-1 1.10 x 10-1 2.82 x 10-1
106.3 379.5 3.20 x 10-1 3.24 x 10-1 2.00 x 10-1 4.55 x 10-1 1.05 x 10-1 2.79 x 10-1
112.2 385.4 3.20 x 10-1 3.12 x 10-1 2.00 x 10-1 4.51 x 10-1 1.00 x 10-1 2.77 x 10-1
65.6 338.8 2.40 x 10-1 2.52 x 10-1 4.00 x 10-1 3.12 x 10-1 7.5 x 10-2 5.11 x 10-1
82.1 355.3 2.40 x 10-1 3.33 x 10-1 4.00 x 10-1 3.29 x 10-1 1.04 x 10-1 5.40 x 10-1
86.7 359.9 2.40 x 10-1 3.24 x 10-1 4.00 x 10-1 3.27 x 10-1 1.01 x 10-1 5.36 x 10-1
91.4 364.6 2.40 x 10-1 3.15 x 10-1 4.00 x 10-1 3.25 x 10-1 9.7 x 10-2 5.33 x 10-1
100.4 373.6 2.40 x 10-1 3.06 x 10-1 4.00 x 10-1 3.23 x 10-1 9.4 x 10-2 5.30 x 10-1
102.2 375.4 2.40 x 10-1 2.88 x 10-1 4.00 x 10-1 3.19 x 10-1 8.7 x 10-2 5.24 x 10-1
105.3 378.5 2.40 x 10-1 2.79 x 10-1 4.00 x 10-1 3.18 x 10-1 8.4 x 10-2 5.20 x 10-1
131.8 405.0 2.40 x 10-1 2.61 x 10-1 4.00 x 10-1 3.14 x 10-1 7.8 x 10-2 5.14 x 10-1
109.4 382.6 2.00 x 10-1 2.10 x 10-1 5.00 x 10-1 2.49 x 10-1 5.9 x 10-2 6.11 x 10-1
115.6 388.8 2.00 x 10-1 2.17 x 10-1 5.00 x 10-1 2.50 x 10-1 6.2 x 10-2 6.14 x 10-1
126.9 400.1 2.00 x 10-1 2.70 x 10-1 5.00 x 10-1 2.58 x 10-1 7.9 x 10-2 6.35 x 10-1
127.6 400.8 2.00 x 10-1 2.40 x 10-1 5.00 x 10-1 2.53 x 10-1 6.9 x 10-2 6.23 x 10-1
134.3 407.5 2.00 x 10-1 2.32 x 10-1 5.00 x 10-1 2.52 x 10-1 6.7 x 10-2 6.19 x 10-1
138.8 412.0 2.00 x 10-1 2.77 x 10-1 5.00 x 10-1 2.59 x 10-1 8.2 x 10-2 6.38 x 10-1

(a) Critical opalescence.

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