Components:
(1) Acetonitrile,
C2H3N; [75-05-8]
NIST WebBook
(2) Undecanoic acid,
C11H22O2; [112-37-8]
NIST WebBook
Original Measurements
Hoerr, C. W.; Ralston, A. W.; J. Org. Chem. 9, 329-37 (1944).
Variables:
Ambient temperature: 273 - 296 K
Prepared by:
Method/Apparatus/Procedure:
The synthetic method, as described elsewhere,1 was used. No details were reported.
Source and Purity of Materials:
- Source not specified; purity not specified; dried and twice distilled.
- Purified according to Pool nad Ralston2; freezing point = 28.13°C.
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
References
1
Hoerr, C. W.; Binkerd, E. F.; Pool, W. O.; Ralston, A. W.; J. Org. Chem. 9, 68-80 (1944).
2
Pool, W. O.; Ralston, A. W.; Ind. Eng. Chem. 34, 1104 (1942).
Experimental Values:
Note: The solubilities of undecanoic acid (2) in acetonitrile (1) in mass percent over the indicated temperature range were reported in graphical form and in a table.Solubility of undecanoic acid (2) in acetonitrile (1)
| T (°C) | T (K) | MR2 (g1/100 g2) | 100w2 | x2 |
|---|---|---|---|---|
| 0.0 | 273.2 | 8.7 | 8.0 x 10-2 | 1.9 x 10-2 |
| 6.1 | 279.3 | - | 1.14 x 10-1 | 2.76 x 10-2 |
| 10.0 | 283.2 | 17.3 | 1.47 x 10-1 | 3.66 x 10-2 |
| 14.8 | 288.0 | - | 2.08 x 10-1 | 5.47 x 10-2 |
| 18.3 | 291.5 | - | 3.47 x 10-1 | 1.05 x 10-1 |
| 19.7 | 292.9 | - | 5.30 x 10-1 | 1.99 x 10-1 |
| 20.0 | 293.2 | 185.0 | 6.49 x 10-1 | 2.90 x 10-1 |
| 20.3 | 293.5 | - | 6.56 x 10-1 | 2.96 x 10-1 |
| 22.8 | 296.0 | - | 8.75 x 10-1 | 6.07 x 10-1 |
(*) The compilers extracted these data from the published graphs.
