Components:

(1) Benzene, C6H6; [71-43-2] NIST WebBook
(2) Water, H2O; [7732-18-5] NIST WebBook

Original Measurements

von Groschuff, E.; Z. Elektrochem. 1911, 17, 348-54.

Variables:

Ambient temperature: 3 - 77 °C

Prepared by:

A. Maczynski

Method/Apparatus/Procedure:

In 1 dm3 long-necked flask (1) was placed and (2) was added dropwise.

Source and Purity of Materials:
  1. Kahlbaum; stored over Na; distilled twice from K-Na alloy; m.p. 5.4°C
  2. not specified.
Estimated Errors:

Ambient temperature: ±1-2 K

Experimental Values:
The solubility of water in benzene
T (°C) MR2 (g1/100 g2) x2
3.0 3.0 x 10-2 1.3 x 10-3
23.0 6.1 x 10-2 2.6 x 10-3
40.0 1.14 x 10-1 4.9 x 10-3
55.0 1.84 x 10-1 7.9 x 10-3
66.0 2.55 x 10-1 1.10 x 10-2
77.0 3.37 x 10-1 1.45 x 10-2

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