SDS Volume (813)

Volume 38. Hydrocarbons in Water and Seawater, Part II, p None

Original Measurements

Eganhouse, R. P.; Calder, J. A.; Geochim. Cosmochim. Acta 1976, 40, 555-61.

Variables:

Temperature: 25 °C

Prepared by:

A. Maczynski

Method/Apparatus/Procedure:

A mixture of 500 mL (2) and 0.001 mol (1) was equilibrated in an Erlenmeyer flask for 12 h (agitation) + 24 h (stationary). The saturated solution, 100 mL was extracted with hexane, concentrated by evaporation under nitrogen and analyzed by glc. A 5700 A Hewlett-Packard instrument equipped with dual compensating columns and flame ionization detectors was employed.

Source and Purity of Materials:
  1. source not specified; analytical grade; used as received; no impurities by glc.
  2. doubly distilled; free of trace organics.

1-Methylnaphthalene with Water

Components:

(1) 1-Methylnaphthalene, $\ce{ C11H10 }$; [90-12-0] NIST WebBook
(2) Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook

Experimental Values:

The solubility of 1-methylnaphthalene in water at 25°C was reported to be 25.8 mg(1)/kg (2) and 1.81 × 10-4 mol(l) L (2).
The corresponding mass percent and mole fraction, x1, calculated by the compiler are 2.58 × 10-3 g(1)/100 g sln and 3.27 × 10-6.

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