Components:
Original Measurements
Jones, J. R.; Monk, C. B.; J. Chem. Soc. 1963, 2633-5.
Variables:
Ambient temperature: Temperature
Prepared by:
Method/Apparatus/Procedure:
Tritiated water was shaken with bromobenzene in 1:10 volume ratios for 4 hours in a flask in a water thermostat bath. The water content was determined by tritium assay. The count rates were determined using a typical liquid scintillator solution technique.
Source and Purity of Materials:
- Tritiated.
- Source not known, laboratory grade, dried over CaCI2 and fractionally distilled before use.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): ±5%.
Experimental Values:
| T (°C) | x1 | S1:2 | C1 (mol/dm3) |
|---|---|---|---|
| 25.0 | 1.92 x 10-3 | 3.4 x 10-1 | 1.88 x 10-2 |
| 30.0 | 2.239 x 10-3 | 3.95 x 10-1 | 2.182 x 10-2 |
| 35.0 | 2.62 x 10-3 | 4.6 x 10-1 | 2.54 x 10-2 |
(a) Reported. (b) Calculated by F. W. Getzen. (c) Calculated by the compiler.
