Compilation - 1-Methylcyclohexene with Water (IUPAC SDS Volume 37)
SDS Volume (502)
Volume 37. Hydrocarbons in Water and Seawater, Part I, p 439
Original Measurements
McAuliffe, C.; J. Phys. Chem. 1966, 70, 1267-1275.
Variables:
Temperature: 25 °C
Prepared by:
Z. Maczynska, A. Maczynski, A. Szafranski
Method/Apparatus/Procedure:
In a 250 mL glass bottle, 10-20 mL of (1) was vigorously shaken for 1 hr or magnetically stirred for one day, with 200 mL of (2) at 25 °C. The bottle was set aside for two days to allow droplets of undissolved (1) to separate. Absence of emulsion was checked microscopically. A sample of the hydrocarbon-saturated water was withdrawn with a Hamilton Syringe and gas liquid chromatograph in conjunction with a flame ionization detector.
Source and Purity of Materials:
- Phillips Petroleum or Columbia Chemical; used as received.
- Distilled.
1-Methylcyclohexene with Water
Components:
(1) 1-Methylcyclohexene,
$\ce{ C7H12 }$;
[591-49-1]
NIST WebBook
(2) Water,
$\ce{ H2O }$;
[7732-18-5]
NIST WebBook
Experimental Values:
The solubility of 1-methylcyclohexene in water at 25°C was reported to be 52 g(1)/106 g(2).
The corresponding mass percent and mole fraction, x1, calculated by the compilers are 0.0052 g(1)/100g sln and 9.7 × 10-6.
